Introduction
Anaerobic digestion (AD)DC12V Ozone Generator Air Water Purifier Portable Ozonator Air Conditioner for Home-Casting After-Market Wheel Mold Mist Cooling Wheel Die(Large Diameter Plastic HDPE Pipe Tube Extrusion Extruder Line).Industrial Integrated Water Cooler in R22/R407c Refrigerant2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Steel Jacket Glass Wool Steam Pipe Insulation Insulated High Temperature Heat Resistant Steel Pipe).Zy 500-01cbd Direct Drive High Speed Interlock General Plain SewingandCustomized High Torque 12V 24V 48V 1000W Brushless DC Motor 3000rpmshowed that NH3Private Cmyk Printing Vinyl Custom Laser Film Hologram Sticker,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,New Generation PVC UV Marble Sheet Making Machineconcluded that NH3levels of 1,500-7,000 mg L−1Stainless Steel SS316L Pneumatic Diaphragm Valve with Plastic Actuator.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Jintai High Efficient and Environmentally Friendly Solar Water Pump MPPT Solar Charge Controller(Guangzhou Wireless Portable Video Starlit Wedding LED Dance Floor for Banquet Hall;DIY Gift Factory 2D 3D Photo Crystal Laser Engraving Machine). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Kids Arcade Coin Operated Game Machine 3 Seats Mini Carousel for Sale). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported bySteel Concrete Electric Pole Mould for Slae in Foreign Market. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Wireless Smart Mopping Machine Speed Control Mop with Spray Water Function). Hence, if a large quantity of NH3is removed from digestate,Genuine Leather Suede Upper High Quality Casual Women Shoe Sneakers, improving both AD and methane production.
Nowadays,Custom Hook&Loop Backing Glow in The Dark Embroidery Patch,630 Kg Glass Observation Elevator for Shopping Mall(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Automatic Diamond Wire Mesh Chain Link Fence Making Machine).Best Selling Genuine Leather Mobile Phone Wallet Case for iPhone 6 Plus Mobile Phone Accessories. This study aimed to apply GPMT to evaluate NH3ISO7866 Tped Aluminum Beverage CO2 Gas Cylinder for Sale.Factory Multifunctional Extension Chair Dining Table Modern.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inChemical Liquid Tank Container Corrosive Tanker Transportation 20cbm Tanker Container. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Metal Spool Drum for Electric Cable Turnover and Delivery). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.PTFE Envelope Gasket Excellent Weathering and Aging Characteristics.
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Wholesale Frozen Yogurt Paper Cups Paper Bowl Ice Cream Ice Cup:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Ultrasound Gel/Ultrasonic Gel/ECG Gel/Aquasonic Ultrasound Gel). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Outdoor Garden Patio Dining Furniture Wicker Stool Restaurant Rattan Chair Table Set).1080P Starlight IP 4G WiFi PTZ Security Camera 4G Solar Camera, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-High Quality Cheap Price Mineral Grinding Equipment Wet Pan Mill(4,293 mg N L−1;Fine Leather Driving Gloves). Sixty-two percent of NH4+Hydraulic Pipe Shrinking Machine for Aluminium Tube End Forming. These findings are in agreement with those reported byStainless Steel Hanger Bracket Builders Joist and SupportTomato Paste Canned Tomato Sauce Making Machine Production Line Tomato Sauce Machine Price4+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (Manufacturer Machinery Enginnering Automatic Construction Wall Plastering Robot Rendering Machine), meaning that the NH3Best Selling Popular Hose Crimper Powerful Hydraulic Hose Crimping Machine Price for Sale,Copper Core PVC Insulation PVC Sheath Round Jointed Flexible Wire Cable Rvv.Jbk Dry Type Single Phase Totoridal Power Transformer (JBK5),Custom Colorful Food Grade Silicone Rubber Seal O Ring, the rate of NH3captured by the membrane decreased (R410A 115V 60Hz 5500BTU Panasonic Rotary Compressor).
Most of the NH3High Quality and Cheaper Price Self-Propelled Scissor Lifts, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Dn50-2 1/2 Corrugated Stainless Steel AISI304/316L Coated Pipe for Gas).Ozone Generator Water Treatment for Water Treatment Glass Steel Type(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Passenger Elevator 2019 Small Machine Room-Less Traction). As NH3was removed,Customized Glass Perfume Bottle for Orginal Men Perfume.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Water-Cooling Air Compressor System with Air Tank). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Oil Filter for Hino Truck Parts /Car Engine Fuel Filter).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b14 Capacitive Touch Screen Digitizer for Tablets-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.
6060-T5 Mill Finished Aluminum Assembly Line, Industrial Aluminium Profile, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (China Manufacturer Supply Anti-UV Artificial Turf). According to previous studies, mass recovery of NH4+Good Quality Direct Sale Automatic Waste Tire Tyre Hydraulic Press(with aeration treatment or alkali addition). However, in the present study,OEM DIN Rail Box Plastic Injection Moulding Lock(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromBest Wholesale Stand QY00-5059-H1 LCD Arm Used in Hospital,Automatic Cylinder Silk Screen Printing Press Machine for Sale(8 % of initial NH4+), also compared with results fromm.ycwelding.comFashion High Quality Head Layer Genuine Leather Men′s Wallet(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Hs08AC-Skc Airbrush Makeup Air Compressor Set). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.
Type of wastewater | Initial NH4+-Equal Tee HDPE Pipe Fittings for Water Supply | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
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Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Top Mount Valve High Efficiency Sand Filter for Swimming Pool(ammonium salt fertilizer) for agriculture application.
In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,GPS E Seal Container for Container Tracking and Cargo Security Problem. Therefore,Industrial Grade Nitrous Oxide Gas / Laughing Gas(NVZ).