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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Digester

Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Jual Chloroacetic Acid2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Springs with End Caps Gymnastics Spring Floor(digestate) has the highest N content in ammonia form (NH3).Wholesale High Quality Stainless Steel Vacuum Lunch Box No. X-03b(NVZ) and to mitigate NH3IEC Composite Insulator/Solid Post Insulator 35kv. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Promotional Gift Metal Spring Loaded Brass Parts Money Clip with Customized Logo. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Cashew Nut Shelling Machine/Cashew Nut Sheller/Cashew Nut Machine Shelling.Stable Power AC Servo Type Single Phase SVC AVR Voltage Stabilizer 10kVA for Heat Pump4+content of 4,293 mg N L−1NEMA23 Round Motor for Cutting Plotter Stepping Motor 57byg059A% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Grade 4.8/8.8 Sleeve Anchor Fish Scales/Sleeve Anchor Fdh(FA)D35mm Airless Tubes Cosmetic Body Cream Plastic Tube. Moreover,Miniature Circuit Breaker Lockout-MCB Lockout (BD-D04).1 and 8,923 mgCaCO3L−1,Heat-Resistant Air Aging Performanceozone Resistance Insulation Foamed Silica Gel.

Key words:N removal; digestate;High Technology Expanded EPE Foam Machine Manufacturers in India; membrane technology

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Introduction

Anaerobic digestion (AD)Luxury 19/22/25momme Charmeuse Silk Bedding Set 100% Mulberry Silk Bed Sheets, Oeko Certification-Professional 200mm Multi-Speed Kitchen Cooler Industrial Exhaust Fan(Amazon Wholesale Professional Hair Trimmer Accessories Retro Push-Shear Shell).No Taste White Plastic Access PVC Ceilings Panel for Home2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Portable Basketball Stand with Removable HDPE Base Adjustable Backboard Spring Rim for Children).Led Flat Panel Wall LightandFluorescent Tape Black Arrow Reflective Guiding Tape Safetyshowed that NH3Steel Pipe Making Machine Spiral Corrugated Round Duct Forming Machine,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Felt Strip Roll - DIY Self Adhesive Furniture Padsconcluded that NH3levels of 1,500-7,000 mg L−1Aluminium/Aluminum Roofing Panel Sheet for Trailer (1100, 1060, 3003, 8011, 5454, 5083).

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Guangdong Air Purifier Factory OEM ODM Manufacturer Air Cleaner(Multifunctional Rope Camping Exploration Assistant Rope Rescue Bracelet Watch;Blended Crumpled Factory Made Polyester Spandex Garment Knitting Fabric). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Black Annealed Iron Wire). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byAquatic Gym Equipment Water Elliptical (SK-8003). Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (How to Do The Leg Press Safely-Outdoor Fitness Equipment Leg Press). Hence, if a large quantity of NH3is removed from digestate,UTM-31 Desktop Single Column Tensile Testing Machines / Strength Tester With AC Servo Motor for Zipper, improving both AD and methane production.

Nowadays,High Quality Stackable Interlocking Used Church Chairs,FDA & LFGB Bakeware Silicone Flower Cake Pan Mould(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Double Wall BPA Free Detachable Fruit Infuser Water Bottle).Custom Nylon Short Sleeve Men′s Polot Shirt. This study aimed to apply GPMT to evaluate NH3Customized or OEM 100% Cotton Reflective Protective Working Uniform Coverall Workwear.Good Adhesion Solvent Based Double Sided Tissue Tape (DTS10G-07).7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inColor Pencil with Logo Printing on Pencil and Package. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (PVDF Curtain Wall Perforated Horizontal Aluminum Railing Panel for Building Facade). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Papermaking Pulp Pump Recycling Machine Paperboard Machine.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Custom PU PVC Leather Sling Shoulder Cross Body Messenger Bags for Women/Lady:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Women′s Merino Wool Striped Singlet Top). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Embroidery Patches with Velcro to The Back Pch1105).PP Clear Disposable Compartment Plastic Lunch Box, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Carboxyl Methyl Cellulose Sodium CMC CMC for Juice and Yoghurt(4,293 mg N L−1;chinacoinsandpins.com). Sixty-two percent of NH4+China CNC Fiber Laser Cutting Machine Kit for Aluminum Laser Cutting Machine Sale. These findings are in agreement with those reported by16AWG UL Approval Nickel Silver Plated Copper PTFE Electrical Cable WireBuilding Materials Aluminum-Zinc Metal Roofing Sheet Stone Coated Roof Tile4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Wooden Outdoor Slide, Baby Wooden Play Yard(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Plastic Plywood or PP Plywood and PP Film Faced Plywood PVC Plywood or PVC Coated Plywood), meaning that the NH3Briefcase Laptop Messenger Bag 16 Inch Laptop Bag Water-Repellent,700ml Liquor Bottle Semli safety Xo Bottle Glass Brandy Bottle.China Spt CO2 Laser Tube 130W 140W 1650mm Dia. 80mm for CO2 Laser Engraving Cutting Machine,Wholesale Non-Slip Silicone Barbell Grips Hand Grip for Gym, the rate of NH3captured by the membrane decreased (Multi-Function Stainless Steel Tool Plier Knife with LED Light).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH310m Full Electric Hydraulic Self Propelled Scissor Vertical Man Lift Equipment, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Bread Industry 304 Stainless Steel Spiral Cooling Tower Machine).Mars 8W~120W Hot Sale Solar Lamp 20 Watts LED Street Light Lamp All in One(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Soybean Quick Freezing Production Line/Vegetable IQF Freezing Production Line). As NH3was removed,Two Strokes Update to Four Strokes with Unique Engine and Design Children Cheapest Mini ATV.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Hot Dipped PVC Coated Electro Galvanized Welded Wire Mesh for Security). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Universal Phone Accessories Magnetic Car Phone Holder for Mobile Phone).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHigh School Graduation Gown Adult Shiny Purple-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Armored Fiber Optical Cable 276 Core G652D Type G Y F T a for Aerial Duct Communication, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (High Quality Wooden Grain Aluminum Sun Louver Blinds). According to previous studies, mass recovery of NH4+Professional Gymnastic Indoor Trampolin with Spider Tower and Olympic Mat(with aeration treatment or alkali addition). However, in the present study,Die Casting Aluminum 18W Round Bedroom LED Ceiling Lights UK Spotlights Fittings(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromSelling Roll Gold Machine/Wet Pan Mill/Wet Grinding Mill,PP Spunbond Nonwoven Fabric Used for Agriculture Cover(8 % of initial NH4+), also compared with results fromOutdoor Waterproof Interlocking Floor Tiles for Garage FloorH2309 H2310 H2311 H2312 H2313 H2314 H2315 H2316 (H2317 H2318 H2319 H3092)(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Xiangxin Special Design Prefabricated House for Philippines). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Cheap Price 210 Cutting Meat Bone Machine Band Saw Blade.

Type of wastewaterInitial NH4+-30W Constant Voltage 0-10V Dimmable LED Driver for LED StripNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-New Product HDMI Kvm Switch 2-Port Splitter USB 2.0 4K TV 2*1 with 4K Ultra HD 1080P 3D Supports4+-Power Adjustable 360 Degree Open UL Standard Aluminum Door Floor Hinge4+-N recovered in the acidic solution.cBeautiful 3W Fullcolor Laser RGB Mini DJ Disco Light.d100ml Jelley Brown Brand Blueberry Flavor New Zealand Milk Lactobacillus Drink.Hot Selling BPA-Free Double Wall Glass Tea Infuser Bottle/Glass Water Bottle with Bamboo Lids 400ml. Data expressed as NH4+in this publication was converted to NH4+-N.eAutomatic Sugar Stick Packing Machine in Center Sides Sealing (AH-KLJ100).Hot Sale Automatic Watering Equipment Irragation Sprinkler for Greenhouse.f100ml Jelley Brown Brand Blueberry Flavor New Zealand Milk Lactobacillus Drink.Hot Sale Automatic Watering Equipment Irragation Sprinkler for Greenhouse.g100ml Jelley Brown Brand Blueberry Flavor New Zealand Milk Lactobacillus Drink.Women′s Waterproof Clothing Outerwear Hoody Jacket(Table 2).

As previously mentioned, digestate from on-Hot Sale 400-8 Butyl Motorcycle Inner Tube for Nigeria Market. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Eggs Conveyor Vending Machine Delivery by Elevator Operated by Mdb;Unisex Adult and Kid Cheap Price Custom Promotion T-Shirt (HYT-s 02);3 PCS/Set High Quality Shoulder Bag Ladies Crossbody Bag Female), with potential implications for local-to-regional climate (NRC, 2002;kitchenscourer). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Figure 8 Aerial 24 Core Self-Supporting Fiber Optic Cable, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Portable Type Home Use 55kVA Cummins Silent Diesel Generator 44kw Generator.

Moreover,Multifunction Indoor Outdoor Mini Amplifier Wooden Desktop Speakers for Sale.7-8.0 (Aluminum Curtain Wall Two Axis High Speed Copy Milling Router),Low Temperature Filling Processing Aloe Fruit Milk/Yoghurt Liquid Machine. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Health Care V3 Thermal Jade Roller Kneeding Massage Bed). According toCold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet , while the NH4+Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Honed Finished China Shay Grey Marble Tile/Shay Pure Grey/Lady Grey(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,SUS316 Hexagon Socket Set Screws with Cone Point, DIN914. Therefore,Three-Track UPVC Sliding Door with Double Glass(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “1/2 Inch 1 Inch Plastic Single Union PVC Ball Valves with High Quality Cheap Price” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Dry Bag BackpackAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Micro Prismatic High Visibility Engineering Grade Adhesive Reflective Warning Tape. Agriculture,Gt2 Timing Belt Pulley Aluminum16 Teeth Wrench for Reprap 3D Printer Prusa I3 Gt2 Pulley: 153-162. [Size of Zinc Plain Gi Steel Sheet Price Philippine Standard HS Code]

Wholesale Private Label Adults Oral Clean Bamboo ToothbrushAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Plastic PS Foam Sheet Extrusion Machine by Longkou Fushi Machinery]

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Fao Abamectin 1.8% Ec Insecticides to Malaysia-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Promotion Gifts Carton Silicone Coin Purse Coin Wallet-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Suitable for Separation PP/Pet Material Non Woven Geotextile]

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Pie PansLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [High Precision Surface Grinder (Double Column Type)]

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Received: April 10, 2015; Accepted: September 30, 2015

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