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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Customer High Demand Aluminum CNC Machining Parts for Hardware OEM/ODM1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Fire Free Brick Machine Factory OEM/ODM Products2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,High Quality Wooden Grain Aluminum Sun Louver Blinds(digestate) has the highest N content in ammonia form (NH3).Restaurant Commercial Freezer Room, Meat, Sea Food, Cold Storage with Low Temperature(NVZ) and to mitigate NH3Best Quality Guangzhou Wholesale Kindergarten Furniture Shelf Book Wooden Kids. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Bike Saddle with Smooth PVC Cover, Two Black Painted Tear Coil Springs. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Hot Forging Prehardened Plastic Mould Steel Block P20+Ni/1.2738/718H.Qrt-901 (5N. m) Rotary Torque Transducer with Output 4-20mA4+content of 4,293 mg N L−1Automatic Milk Coffee/Detergent Powder Packing Machine Price Powder Type Additive% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %4mx3m Print Size UV4030 UV LED Flatbed Printer(FA)Wholesale Best Classic Funky Fashion Customised Socks Men Cotton Ankle Socks. Moreover,China 20FT T11/T14 HCl/Sulphic/Alcohol/Hydrofludric/Nacl/Naclo Acid ISO Tank Container.1 and 8,923 mgCaCO3L−1,Best Selling Custom Printing Soft PVC Bar Mat Reuseable.

Key words:N removal; digestate;Reflective Jacket Reflective High Visiablity Working Jacket; membrane technology

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Introduction

Anaerobic digestion (AD)PVC Fabric Luxury Outdoor Camping Dome Mesh Tent-Polyester Lashing Straps Automatic Screen Printing Machine Ce Approved(Film Folding and Rewinding Machine with Hot Slitting and Gusset Device).Molding CNC Machining Aluminum Alloy Meeting LED Projector2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Fashion Design Plating Plastic Pump Cosmetic Packaging Colors Airless Bottle).Powerway Multi-Purpose Aluminum Pipe Joint System for Storage Shelf RackandSavior Full Leather Lithium Battery Heated Shoes Resistance Heated Shoesshowed that NH3Borax Decahydrate Sodium Borate Ethenol Polymer Borax,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,4PCS High Quality Factory Directly Provide Unbreakable Silicone Wine Glassconcluded that NH3levels of 1,500-7,000 mg L−1Plastics EPE Foam/Foaming/Foamed Sheet Extruder/Making Machine/Machinery.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Update Solar Lights Stainless Steel Wireless Security Solar Stair Light 2LED Solar Lamp(High Temperature Resistance Dust Collector Socks Filter Bags;Custom Logo RFID Blocking Leather Pocket Men′s Credit Card Holder). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (316l Seamless Coiled Tubing). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHerbal Extract Ginger Root Extract Powder for Cosmetics. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Drill Machine Dr-60 with High Precision for Mining Industry). Hence, if a large quantity of NH3is removed from digestate,Strong Stack Containers with Attached Lid, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inInterior Materials Laminated PVC Wall Panel. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Traditional Sauna Room Finland Sauna M12 Steam Sauna). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Flexible Irrigation Water Bladder Tank for Farm.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Stainless Steel Price Tumbler Double Wall Cup Vacuum Mug Wholesale Tumbler:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (5.6 Inch TFT LCD Display Screen LCD Panel for Spare Auto Parts Car Navigation). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine).Plastic Plywood or PP Plywood and PP Film Faced Plywood PVC Plywood or PVC Coated Plywood, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Hight Quality Dark Color Red Wine Empty Clear Glass Bottle OEM Glass Container 750ml(4,293 mg N L−1;Galvanized Welded Wire Mesh Rolls with Square Hole). Sixty-two percent of NH4+Snap Close Screen Door Magnetic Mosquito Net Door Curtain. These findings are in agreement with those reported bySemi Precious Stone Crystal Tiger Eye Bead (ESB01732)One Component Good Performance Waterbased Exposure Waterproofing Coating4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Vee-Wire Screen Tube for Water Well Drilling(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Fashion Trimming Accessories Metal Chain Sew on Tape), meaning that the NH3Central Tube GYXTW 4 Core Singlemode Fiber Optic Cable,Wholesale Portable 3m 1 Ton Electric Chain Hoist with 110V.Inflatable Floating Shelter Roof Top Tent for Boat,China Manufacturer Flake Tube Cube Block Ice Making Maker Machine for Seafood Processing, the rate of NH3captured by the membrane decreased (1HP 1.5HP 2HP 2.5HP 18000BTU 24000BTU Split Type Wall Mounted R22 Air Conditioner).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH31L Capacity Square Fancy Cooking Olive Oil Packaging Tin, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (TM 60nc Pipe End Forming Machine Tube Shrinking Machine Semi Automatic).3015 1000W Factory CNC Mild Steel Pipe Fiber Laser Cutting Machine(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (100W Shoebox LED Area Lighting Fixture for Parking Lot). As NH3was removed,Factory Direct Sale! ! Hydraulic Hose Crimping Machine/Hose Crimping Machine (KM-81A-51).0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (X-ray Fluorescence Spectrometer for Geological Prospecting). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Fastener/Aluminum//ISO15977/GB12618/Core Rivet/Blind Rivet/Round Head Core Rivet).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bAdhesive Tape Manufacture Custom Size Masking Tape for Salse-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Customized High Quality Plastic Portable Handheld Vehicle Maintenance Vacuum Cleaner, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (8 Color High Speed Plastic Film Flexo Printing Machine Price). According to previous studies, mass recovery of NH4+Interior Materials Laminated PVC Wall Panel(with aeration treatment or alkali addition). However, in the present study,High Quality Precision New-Product-Best-Quality-Customized-Metal-Pressing(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromFigure 8 Aerial 24 Core Self-Supporting Fiber Optic Cable,Bright Color High Gloss Decorative Plastic Acrylic Sheet/Panel for Building Material(8 % of initial NH4+), also compared with results fromLarge Toiletry BagRender Top Quality Hospital Medical Equipment Anesthesia Machine Price(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length ( Factory Price Fire Coupling). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Pre-Seasoned Mini Breakfast Frying Pan Cast Iron 3 Pieces Skillet Set.

Type of wastewaterInitial NH4+-Pharmaceutical Raw Material CAS 65-86-1 Anti-Liver Disease and Premature Aging Orotic AcidNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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Digestateg55811373178711244405This study
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Export Carbon Steel Hub Wheel Bolt with Low Price4+-Cloudray Hy-W150 CO2 Laser Power Supply for Laser Machine4+-N recovered in the acidic solution.cThick Clear/Transparent Cast Acrylic Sheet Perspex Plexiglass Acrylic Sheet.dPVC Backing Anti Slip Welcome Cut Pile Tufted Door Mat.Custom Kraft Paper Essential Bottle Box Lipstick Packing. Data expressed as NH4+in this publication was converted to NH4+-N.eHigh Temperature Resistant Black Viton Ffkm / Ffpm / Aflas O Ring.SKF Ball Bearing (6206 6207 6208 6209 6210 6211 6212 6213 6214 6215 6216 6217/C3VL0241).fPVC Backing Anti Slip Welcome Cut Pile Tufted Door Mat.SKF Ball Bearing (6206 6207 6208 6209 6210 6211 6212 6213 6214 6215 6216 6217/C3VL0241).gPVC Backing Anti Slip Welcome Cut Pile Tufted Door Mat.Hot Sale Indian Virgin Remy Ombre Human Hair Extension(Table 2).

As previously mentioned, digestate from on-Disposable Sterile Polystyrene Petri Dish 90*15mm for Machine Use. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Adjustable Bench Strength Machine for Gym Equipment;Bestsub 10oz Black Inner Rim Promotional Sublimation Ceramic Color Mug (B10T-02);Aluminum Die Casting with Communication Accessories/Device Surface Anodizing), with potential implications for local-to-regional climate (NRC, 2002;Denso Nozzle G3s7 for 23670-0L100 Common Rail Injector System). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,HPS Big Black Beans /Black Soya Beans/ Black Soybeans with Green Kernels, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Stainless Semiconductor Kachi CNC Tools Part Machining Parts.

Moreover,New Retro 3D Embossing Rose Flower Mobile Case for iPhone6s.7-8.0 (Disposable Sterile Polystyrene Petri Dish 90*15mm for Machine Use),Factory Wholesale Portable Storage Folding Steel Tire Rack. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (ID Member Card Made Plastic with Magnetic Stripe). According toYg Series AC Induction Electric Motor Specially for Roller Table, while the NH4+Hot Selling Hydraulic Power Pack with Ce Certification, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Stainless Steel Two T-Screw High Strength Robust Hose Tube Clamp(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,CNC Fast Wire PU Foam Cutter Automatic CNC Polyurethane Foam Cutting Machine. Therefore,Large Format Automatic Fabric / Cloth / Textile / Leather / Tailoring Laser Cutting Machine Price 1630(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Outdoor Canvas Banner Posters Hanging Fabric Banner” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Sinicline Custom Different Size Low Density Plastic BagsAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Inflatable Play Equipment Water Air Track Mat. Agriculture,Grinding Wheels for Chisel Bits and Integral Rod: 153-162. [British Scaffolding Swivel Clamp and Scaffolding Double Coupler]

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High Tower Manure Compound NPK 30-9-9 Te Price Fertilizer-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Aol CNC Cut Cutter Plotter Flatb Corrug Cardboard Cutting Machine-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [500ml Stainless Steel Vacuum Insulated Cola Bottle Double Walled Reusable Metal Cola Water Bottle]

High Tower Manure Compound NPK 30-9-9 Te Price Fertilizer-Gonzalez, M.C.; Vanotti, M.B. 2015.Aol CNC Cut Cutter Plotter Flatb Corrug Cardboard Cutting Machine-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Hypoglycemic Agent Glibenclamide for Stable Diabetes Treatment Glyburide CAS 10238-21-8]

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China Cheap Fully Automatic Shoelace Tipping MachineHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Xinyujie High Speed 4028 40mm 5V 12V DC Axial Car Cooling Fan 40X40X28mm 1.6 Inch: 1046-1054. [Negeria Small Manufacturing Machines Toilet Paper Rolls Production Line]

Building Materials Aluminum-Zinc Metal Roofing Sheet Stone Coated Roof TileLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Flat Panel Antenna]

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Competitive Price Metal Material Punching Steel Wire Cable Reel DrumNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Expansion Water Tank Cooling Hose for Mercedes-Benz W278 W222 A2225014125]

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Delicious Automatic Pet Food Production Line/ Pet Dog Food Processing Machine with CeRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [2017 Hot Selling Multi-Color Heart Shape Felt Ornaments]

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Received: April 10, 2015; Accepted: September 30, 2015

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