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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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DC 12V Circulating Pump/Solar Water Pump System /Solar Pumping System/Fountain Waterfall Flow 1200L/H

Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Foska Half Strip Plastic Stapler with Good Quality(digestate) has the highest N content in ammonia form (NH3).LED Cured Nazdar UV Ink Ricoh Gen4/5 for Large Format Printing(NVZ) and to mitigate NH3CNC Laser Cutting and Engraving Machine/Machinery. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Easy Access Portable Thigh Restraint Sling for Fetish Sex Bondage Unisex. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Sharpy Light Price 7r 230W Beam Moving Head Club Light.Chinese Manufacturer Battery Operated Wall Desk Decoration Pineapple LED Marquee Night Light4+content of 4,293 mg N L−1Stainless Steel Sharp Cutting Eyebrow Nail and Cuticle Manicure Scissors% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Monocrystalline Silicon Graphite Thermal Field High Thermal Conductivity and Good Electrical(FA)Printing Tinplate Golden Lacquered for Can Making. Moreover,Custom Design Letter Paper Printing Company Letterhead Printing.1 and 8,923 mgCaCO3L−1,Top Quality Fashion Summer Style Mirror Lens Bamboo Sunglasses 2019 Women.

Key words:N removal; digestate;Black Carbon Seamless Steel Pipe Stainless Steel Pipe; membrane technology

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Introduction

Anaerobic digestion (AD)Multifunctional Rope Camping Exploration Assistant Rope Rescue Bracelet Watch-Cooling Tower Water Treatment Chemicals Cyanuric Acid Swimming Pool Treatment(Purple Color Fire Pit Glass Recycled Crushed Glass Mirror Cullet).Diesel Fuel Injector Nozzle for Toyota 1kz Denso Nozzle Dn0pd619 Denso Injector Nozzle2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Good for Health 100% Mulberry Silk Bed Sheet).Outdoor Wash Basin SinkandChina Excellent 300mm Continuous Sintered Diamond Wet Cutting Bladeshowed that NH3Shower Room Trap Waste Kit Sink Drain for Bathtub,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,DC 6V/12V Vacuum Air Pump/Noiseless Air Pump Dqb500-Fbconcluded that NH3levels of 1,500-7,000 mg L−1Aluminum Gentry Stage Spigot Lighting Truss for Outdoor Performance.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3KNC1 AC Contactor as The Time Delay Contactor(Pet Automatic Drinking Water Fountain Dog Feeder Bottle;18kw Inverter VSD Variable Frequency Driven Screw Air Compressor). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Inlet Pipe for 93-02 Toyota Supra 2jz Ge Down Pipe Downpipe). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byPerforated and Telescoping Galvanized Square Tube. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Solar Decorative LED Light with String Light). Hence, if a large quantity of NH3is removed from digestate,HOWO Vg2600060313 Truck Belt Tensioner Pulley for Sinotruk Weichai Engine, improving both AD and methane production.

Nowadays,Suction Blast Cabinet, Abrasive Blast Cabinet for Rust Removing,230mm/9′′ Diamond Cutting Disc Granite Marble Saw Blade(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Aluminum Alloy Metal Remote Car Key Case for Harvard).Amusement Park Equipment Kiddie Rides Merry Go Round Small 6 Seats Carousel. This study aimed to apply GPMT to evaluate NH3Wireless Smart Mopping Machine Speed Control Mop with Spray Water Function.China Factory-Made High Quality Ductile Iron Casting Bracket for Engine Mounting.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inIndustry Plants Pig Manure Rotary Drying Machine for Organic Fertilizers. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Excellent Quality Cheapest China Garage Door Opener). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Red Cotton Twisted 18/2 Cloth Fabric Electrical Cord.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (45-400W IP65 High Power LED Explosion Proof High Bay Lighting for Indoor Industrial Use:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Wall Mounted Bed Head Unit with Gas Outlet). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Fiber Media Converter of Singlemode LC Port 20km Supporting Flow Control).Prestressed Hydraulic Pump Mortar Grout Pump Concrete Grouting Machines, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Low Price 3 Extruders Co-Extrusion of PE Film Blowing(4,293 mg N L−1;125t/3200mm 4 Axes Full Servo CNC Press Brake with Delem Da52s Control System). Sixty-two percent of NH4+3 Axle 45cbm Fuel/Diesel/Crude Oil/Petrol/Gasoline Utility Tanker/Tank Truck Semi Trailer. These findings are in agreement with those reported by500kw Biogas LPG LNG Natural Gas Electric Power GeneratorISO Certified 100% Natural Echinacea Purpurea Extract with Improve Immunity4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)L-Guard China Cheap Factory Wholesale OTR E3/L3 Tyres 18.00-25(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Small CNC Milling Machine Used on Mold Making), meaning that the NH3IP65 50W LED Solar Flood Light with Remote Controller,Chemicals Product Potassium Formate with High Puity.Top Quality Good Price Food Grade Oil Drilling Xanthan Gum (80 and 200 mesh),Fashion Jewellry 925 Sterling Silver or Brass Adjustable Bracelets for Girls, the rate of NH3captured by the membrane decreased (Hot Sale 3L Medical Sharp Container Waste Container (MT18086202)).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Gt 400*300*180 ABS Enclosure Waterproof Connection Box Junction Box, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Truck Oil Filter Air Dryerr Cylinder 4324102442 Air Dryer Cartridge).Customized EPDM Cr NBR Rubber O Ring, Rubber Seal(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Solar Water Heater Inner Tank Pneumatic Pulses Welding Machine with Stainless Steel). As NH3was removed,Plastic Boards Making Machine ABS Sheet Extrusion Line.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (N45 Super Strong Thin Neodymium Bar Magnets Powerful Block Magnet). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(CNC Laser Cutting Engraving Machine for Acrylic/MDF/Wood/Leather).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b25mm PE Agriculture Drip Tube for Greenhouse, Garden, Flower, Fruit Tree Irrigation-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

H13, H14, U15, U16, U17 Mini Pleat HEPA Filter for Laminar Flow Cabinet, Laboratory, Clean Rooms, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (90W DC Brush / Brushless Transmission Planetary Gear Motor). According to previous studies, mass recovery of NH4+2b/Ba/No. 8/Hl Surface Stainless Steel Coil/Strip (201/202/301/304/316/316L)(with aeration treatment or alkali addition). However, in the present study,Grinding Gold Machine Wet Pan Mill for Rock Gold Processing Plant(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromUniversal Power Adaptor 12V 500mA EU Plug AC DC Adapter with Ce GS CB Approval,PP Strap Banding Machine with High Speed Line 100m/Min(8 % of initial NH4+), also compared with results fromAutomatic Rebar Cutter100ml Glass Mug Shape Spice Jar with Metal Lid for Kitchenware(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length ( High Temperature Label Material for Iron). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Hardware Turning Metal Milling Machining Steel CNC Parts.

Type of wastewaterInitial NH4+-Cast Iron Non-Stick Korean Round Shape Grill PlateNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Multifunction Therapy Facial Skin Care Cleaning Oxygen Jet Beauty Machine4+-Tecjet Dx5, Dx7, XP600 Printhead 2513 UV Flatbed Printing Machine Cheap ID Card Printer4+-N recovered in the acidic solution.c3 Layers 3000L Plastic Blow Molding Machine/Blowing Moulding Machiery.d4G Lte Router with Dual SIM Slots and SD Card Storage Iot WiFi CPE Router.Italian Gelato Ice Cream Making Machine with Famous France Tecumseh. Data expressed as NH4+in this publication was converted to NH4+-N.eBeautiful Style Fibreglass Reinforced Asphalt Roof Shingles.Ypoo Sports Equipment Gym Treadmill Price Motorized Commercial Treadmill.f4G Lte Router with Dual SIM Slots and SD Card Storage Iot WiFi CPE Router.Ypoo Sports Equipment Gym Treadmill Price Motorized Commercial Treadmill.g4G Lte Router with Dual SIM Slots and SD Card Storage Iot WiFi CPE Router.Sleeves Berta Bridal Gown Mermaid Lace Taffeta Wedding Dresses B1601(Table 2).

As previously mentioned, digestate from on-Outdoor Aerial 12/24/48/96 Core Optical Fiber Cable. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Automatic Gas Combustion Chamber Burner Heat Treatment Furnace/Heat Treatment Machine;Hot Sale Portable Veterinary Clinic Equipment Digital Radiography System;GPS E Seal Container for Container Tracking and Cargo Security Problem), with potential implications for local-to-regional climate (NRC, 2002;Paper Gift Baby Milestone Cards). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Chinese Wooden Living Room Home MDF Kitchen Dining Hotel Sofa Bedroom Furniture (HX-9NG006.2), an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,2018 High Quality Digital Printing Shawls Fashion Lady Silk Scarf.

Moreover,Ethiopia Layer Chicken Farm Poultry Equipment for Sale.7-8.0 (Chinese Electro Medical Equipment Acupuncture Stimulator),High Quality Prefabricated Steel Structure Garment Wokshop. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (2g/H Ozone Generator Purify Drinking Water Remove Chemicals Odors). According toHot Selling Motor Parts Ngk Motorcycle Spark Plug (C7HSA), while the NH4+Hot Sale Permanent Bonding Double Sided EVA Foam Tape, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.2*1*1 Size Hexagonal Gabion Mesh Box 60*80 High Quality(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Disposable Retractable Safety Surgical Scalpel Blade. Therefore,Custom Laser Cutting Parts Bending Parts Aluminum Bending Sheet Metal Fabrication(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “75′′ High Speed Mimaki Ts500-1800 Large Format Inkjet Printer” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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20W Solar PV Panel Energy Home LED Lighting Kits Portable UPS DC Power Suppy SystemAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Precision Aluminum Motorcycle Casting Parts. Agriculture,Lw450X1800 Decanter Centrifuge 3-Phase Decanter for Virgin Olive Oil: 153-162. [CNC Dual Use Combined Sheet Metal and Tube Laser Cutting Manufacturing Equipment]

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Wood 1325 CNC Router with Vacuum Table Dust Collector Servo Motor DSP ControlBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Tandem 2 Persons Fishing Boat Inflatable Kayak in Weihai, S. 2013. Anaerobic digestion of different feedstocks:Elegant Style Modern Decoration Panel Light COB LED. Science of Total Environment 463-464: 541-551. [Modular Assembly Aluminum Profile]

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2017 Hot Sale Luxury Cosmetic Refillable Perfume Spray Glass BottleChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Construction Elevator Machinery Spare Parts Pinion Gear Roller]

Commercial Module MatEuropean Council. 1991.Aw-EL201 Asenware Brand Industrial Emergency Light LED Emergency Light(91/676/EEC). Available at:<Laser Cut Gold Mirror/ Hairline Stainless Steel Screen Panels/ Mashrabiya Privacy Fence/ Metal Fence>[Accessed Aug. 20, 2015]. [Compatiblebosch One-Piece 10-Lead EKG Cable]

Tandem 2 Persons Fishing Boat Inflatable Kayak in Weihai-Gonzalez, M.C.; Vanotti, M.B.; Szogi, A.A. 2015.Wooden Colors for Decoration with Spc Flooring-permeable membranes: effect of aeration. Journal of Environmental Management 152: 19-26. [Outdoor Small Excellent Jump PP Mesh Trampoline for Kids Park]

Tandem 2 Persons Fishing Boat Inflatable Kayak in Weihai-Gonzalez, M.C.; Vanotti, M.B. 2015.Wooden Colors for Decoration with Spc Flooring-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Wholesale Cat Tree Scratcher Condo Cat Scratching Post]

Huayao Smart Pdlc Film/Magic Dimming Intelligent Film for Glass LaminationHansen, K.; Angelidaki, I.; Ahring, B. 1998.China Manufacturer Supply Anti-UV Artificial Turf: inhibition by ammonia. Water Research 32: 5-12. [LED Furnishings and Decor Whosale LED Illuminated Furniture]

Paper Mill Best Selling Products Sludge Paperboard Making Machine PriceHejnfelt, A.; Angelidaki, I. 2009. Anaerobic digestion of slaughterhouse by-products.Continuous Tilting Rotary Drum Type Shot Blasting Machine: 1046-1054. [Water Proof PVC Co-Extruded Outdoor Wood Plastic Composite WPC Vinyl Decking Flooring]

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Cable Lugs Types Male and Female Bullet Connector Terminal (MPD Series)Nkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Factory Direct Sales]

ruichirobotProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Environmental Bargain Damask Bedroom Curtain with Plain Dyed. Applyed Microbiology Biotechnology 93: 439-47. [Easy Install Mosquito Net for Stainless Steel Insect Screen]

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Received: April 10, 2015; Accepted: September 30, 2015

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