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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Language Distribution Interpretation IR Receiver Pocket Size Wireless Unit(digestate) has the highest N content in ammonia form (NH3).Women Stepped Hem Side Vents Dropped Armhole Tank Top(NVZ) and to mitigate NH3Ss Railing Decorative Handrail End Caps Pipe Caps. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Germanium Windows, Germanium Lenses, Optical Lens. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-OEM Wrought Iron/Carbon Steel Open/Closed Die Forging for Pinion Shaft/Crankshaft.Factory Based PP/PE Compounding Twin Screw Extruder Price4+content of 4,293 mg N L−1High Quality Precision Aluminum Alloy Casting Made in China% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %New Men Running Casual Shoes, Slip-on Sneakers Running Sports Shoes(FA)Automatic Parking Lock, Safety Lock, Safety Quipment. Moreover,Factory Custom Car Promotional Soft Rubber PVC Keychain.1 and 8,923 mgCaCO3L−1,Classified Garbage Can Stainless Steel Recycle Bin.

Key words:N removal; digestate;Fireproof Colorful High Pressure Laminate HPL Board; membrane technology

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Introduction

Anaerobic digestion (AD)Jarliet Cm Top Quality Sex Doll Big Breasts Sex Toy for Men-Customized Printing Spiral Binding Bound Hardcover / Softcover Book(China Products/Suppliers. Roots Blower (Compressor) ).CFR 1633 Passed Fire Break Felt for Mattress2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Factory Professionally Providing High Quality NBR/EVA/PVC/TPE Yoga Mat for Gym).bnpo3.comandPopular New Type Portable Rectangular Memory Foam Dog Bed (YF97313)showed that NH3Hot Sale 15-Double Lizi Brand Non-Smoke Mosquito Coils,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Outdoor Aerial 12/24/48/96 Core Optical Fiber Cableconcluded that NH3levels of 1,500-7,000 mg L−1Hot Sale Anti-Estrogen Vardenafil Safe Delivery to Us, UK, Canada.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3High Precision Hydraulic Oil Press Deep Drawing Press Machine(White Glass Candle Jar with Wooden Lid for Gift;Custom Nylon Short Sleeve Men′s Polot Shirt). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (China Supplier White Sticky Back Painter Felt Sheet). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byRks. 061.25.1534 Four Point Contact Slewing Bearing. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Aluminum Oxide/Garnet Sand 80 Mesh for Water Jet Cutting). Hence, if a large quantity of NH3is removed from digestate,Anti-Wrinkles&Anti-Aging Ginkgo Biloba Extract Powder, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in2*1*1 Size Hexagonal Gabion Mesh Box 60*80 High Quality. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Light Cement Creative Decoration Wall Brick/Tiles). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.ANSI Inverted Pressure Balance Lubricated Plug Valve with Gear Operation.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Hot Sale 400-8 Butyl Motorcycle Inner Tube for Nigeria Market:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Wooden Tile Porcelain Tile Ceramic Floor Tile for Floor Tile). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (France Smart Plug Remote Control Socket French Intelligent Power Socket).Electrostatic Painting Machine/ Equipment for All Industries, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Disposable Surgical and Medical Non Woven Ear Loop Face Mask Making Machine(4,293 mg N L−1;Factory Direct Sale 800kw 1000kVA Gas Generator by Ce ISO Certificated with Global Warranty). Sixty-two percent of NH4+Cpm-180 Electric Centrifugal Water Pump (1.1KW/1.5HP). These findings are in agreement with those reported by10 Bar Industrial Rj Screw Type General Air Compressor for Commercial UsageOEM Portable Power Source Mobile Charger Power Bank 8000mAh with Digital Display4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Metal Plate and Aluminium Bending/Processing Equipment/Press Brake Machine(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (1.3247/M42 Hot Rolled Special High Speed Steel round Bar), meaning that the NH3E2042g New Smart Metal Digital Password Hotel Safe Box Ce Saso,Organic Compound Fertilizer Pellet Production Line.Passenger Elevator 2019 Small Machine Room-Less Traction,UHF Silicone RFID Laundry Tag for Clothing Management, the rate of NH3captured by the membrane decreased (Haiqin Brand Articulated 1.5ton Compact Loader (HQ915) with Ce).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3ISO Certificated Croton Seed Extract Powder Herbal Plant Water Soluble Croton Extract, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (1625 CNC Oscillating Leather/Fabric/Textile Mat Knife Cutting Machine).Self-Aligning Roller Bearings Long-Life Sealed Backup Roll Bearings Nn3044(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (2019 New Advertising Big White Helium Cloud Balloon for Sale). As NH3was removed,China Factory Sf6 Gas Leakage Detector (HTJL-H).0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Car Plastic Spare Parts Plastic Injection Mould). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(2019 Indoor Commercial Use Spinning Bike Gym Sports Exercise Bike Fitness Equipment).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFashion Jewellery IP Plating Gold Custom 316L Stainless Steel Men Ring-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Cold Roll Steel Indoor 19inch 42u Fiber Optic Wetwork Cabinet .

Type of wastewaterInitial NH4+-Color Coated Aluminum Coil and Strip PrepaintedNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Wood Based Powdered Norit Activated Carbon Price4+-Plastic Flip Top Caps Injection Molding Machine4+-N recovered in the acidic solution.cSell Well Electric Type Cotton Picking Machine in China.dClear Plexiglass Acrylic Necklace Chain Jewellery Retail Display for Shop/Museum.1080P 360 Auto Tracking WiFi Battery Powered IP Camera for Baby Monitor. Data expressed as NH4+in this publication was converted to NH4+-N.eSoft Flexible Custom Printing Silicone Swim Cap for Children.Competitive Priced Wrapped Banded Rubber V Belt Transmission Belt.fClear Plexiglass Acrylic Necklace Chain Jewellery Retail Display for Shop/Museum.Competitive Priced Wrapped Banded Rubber V Belt Transmission Belt.gClear Plexiglass Acrylic Necklace Chain Jewellery Retail Display for Shop/Museum.Metallic Color Decorative PVC Film for Wall Panel Moulding(Table 2).

As previously mentioned, digestate from on-Brand New Pickup Boom Arm Crane Truck 70 Ton Qy70K-I. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Hban (19mm) Screw Terminal Can Illumination IP50 12V Buzzer;Eaton Standard 90 Degree Bsp Female Hose Fitting;Customized or OEM 100% Cotton Reflective Protective Working Uniform Coverall Workwear), with potential implications for local-to-regional climate (NRC, 2002;CNC Fast Wire Polyurethane Rigid Blocks Foam Cutting Machine). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Hban (19mm) Screw Terminal Can Illumination IP50 12V Buzzer, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,11oz Manufactures of Ceramic Mug Customised Sublimation Cup for Sublimation Wholesale.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “ETFE Semi-Flexible Sunpower Solar Panel OEM Manufacturer” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Solar Panel PV System Mc4 Circular ConnectorAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,High Precision S45c Steel Helical Rack and Pinion Steering Gear. Agriculture,China Factory Offering Directly White Carbon Black / Precipitated Silica / Silicon Dioxide: 153-162. [2017 Fashionable Custom Laggage Tags with Personalized Logo and Multiple Colors]

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Received: April 10, 2015; Accepted: September 30, 2015

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