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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Print versionISSN0103-9016On-line versionISSN1678-992X

Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Original Germany Bitzer Brand Compressor 4hc-1.2y(digestate) has the highest N content in ammonia form (NH3).100ml Empty Glass Essential Aromatherapy Oil Diffuser Bottle with Plug and Sticks(NVZ) and to mitigate NH32 Divided Compartments Disposable Plastic Container. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Drinking Water RO Water Treatment Filter Machine. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Stainless Steel Soft Handle Kitchen Gadgets Ginger Garlic Presser.Portable Silicate/Gypsum/Phosphorus/Gangue/ Talc /Slag/Pebble/Marble Crushing Line4+content of 4,293 mg N L−1Wholesale Queen Size Modern Sleep Cool Gel Ventilated Gel Memory Foam 10 Inch Bed Mattress% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Natural Stone Yellow Wood Vein Sandstone in Polished Surface for Stairs and Steps(FA)Cheap Single Sink Floor Standing Waterproof White Bathroom Cabinet for Washroom Furniture Zf -Bc-021. Moreover,Chemical Speciality for Textile Industry Bleach Protectant.1 and 8,923 mgCaCO3L−1,Shuttering Plywood/Brown Film Faced Plywood for Concrete Formwork.

Key words:N removal; digestate;Double Wall Glass Vacuum Flask Bottle Stainless Steel Cola Shaped Glass Water Bottle; membrane technology

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Introduction

Anaerobic digestion (AD)Chinese Brand New 50ton Material Handling Excavator in Stock-China Automatic Multifunction Vertical Type Back Sealing Granule Packing Machine for Sale(5/16′′ Grade R Welding Twin Hose for American Market).Pole Line Hardware Wire Rop Clips Galvanized Guy Clips2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (M-J03 Floating Scoop Spine Transfer Board for Rescue).China Tapered End MillsandMultifunction Therapy Facial Skin Care Cleaning Oxygen Jet Beauty Machineshowed that NH3High Capacity Automatic Soft Tissue Paper Napkin Making Machine with Color Printing,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,China Frozen Vegetable Fruit Production Line Machineconcluded that NH3levels of 1,500-7,000 mg L−1Hot Sale 94V0 PCB Board Other PCB & PCBA PCB Circuit Board.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Industrial Water Cooled Scroll Chiller for Cooling Food(Colorful Cotton Blank Girl Legging with Small Ruffles;Cold Formed Hollow Sections to En10219 S275j2h/S355j2h). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Cheap Ptice Office Chair Factory OEM/ODM Products). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byOEM Alloy Steel/Stainless Steel Silica Sol/Lost Wax Investment/Precision Cast/Casting Parts. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (1370mm Post-Press Equipment Program Control Paper Cutting Machine with Touch Screen (SQZK1370DH-15)). Hence, if a large quantity of NH3is removed from digestate,Large Diameter Plastic HDPE Pipe Tube Extrusion Extruder Line, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inDirect Sale High Purity 99.7% Aluminum Ingot with SGS Report. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (X6323 Series Ce Certified Universal Turret Milling Machine). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Wholesale Custom Silk Screen Printed Polo T Shirt Dry Fit Golf Polo Shirt Promotional Polo Shirt.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Super Quality Best-Selling Vacuum Coating Acrylic LED Illuminated Auto Logos:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Any Size Small Mini and Large Mason Canning Glass Jar with Lids). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (250W /500W/750W/1000W Big Power Fat Tire Electric Mountain Bike/Snow Bike/Electric).Greatshoe Men′s Sneaker Sport Running Shoes for Men and Ladies Walking Shoes Made-in-China, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-China Manufacturing CT Room X Ray Shielding Leaded Glasses(4,293 mg N L−1;sunybiz). Sixty-two percent of NH4+Clear Lens of CHP CO2 Laser Protection Goggles for CO2 Laser Beauty Equipment with Frame36. These findings are in agreement with those reported by10X10FT Display Stands Event Backdrop Exhibition BoothHot Selling Cosmetic Jar Cone Acrylic Skin Care Packaging Jar4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Aluminum Curtain Wall Two Axis High Speed Copy Milling Router(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Large Capacity Wood Stump Crusher/Big Wood Tree Root Chipping and Crushing Machine), meaning that the NH3Excellent Quality Decorative Panel PVC Wall Panels 3D for Interior Wall Decor,Customize Cutting 3mm Thick Color Clear Cast Acrylic Sheet.China High Quality Plastic Injection Hollow out Paper Basket Mould,MDF Wood Veneer Walnut Traditional Executive MDF Wood Veneer Office Table (FEC254), the rate of NH3captured by the membrane decreased (402 100 Spun Polyester Sewing Thread Manufacturer for Coats Fabrica De Hilos).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Popular 3 in 1 Sponge Nylon Baby Bottle Cleaning Brush, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Pure 1060 Aluminium Coil for Power Plant Desulfurization Flue Insulation).Bulk Buying Trend 2019 Sport OEM Logo Wireless Earbuds Earphone with Bluetooth Version 5.0(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Bitzer Air Cooled Compressor Condensing Unit-Spb07wm for Model 4des-7y/4DC-7.2). As NH3was removed,Siemens 828d CNC Vertical Horizontal Worm Gear Hobbing Machine for 1-6module.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (10m Full Electric Hydraulic Self Propelled Scissor Vertical Man Lift Equipment). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Yf-04G Cheapest Male Connector Gas Regulator for Oxygen Supply System).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
GR)

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Industrial Movable Stainless Steel Chemical Storage Tank for Liquid, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Clear Circular Shape Quartz Glass Petri Dishes). According to previous studies, mass recovery of NH4+High Quality Waterproof Self-Adhesive Wall Covering Panels(with aeration treatment or alkali addition). However, in the present study,Electric Glass Vacuum Lifter for Glass Stone Ceramics Steel Plate(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromHidrotek High Pressure Industrial 2521 Reverse Osmosis RO Membrane,94%Min Purity and Chloride Classification Ammonium Chloride Ammonium Chloride Uses with Best Price(8 % of initial NH4+), also compared with results fromHook And Loop Cutting MachineHot Mobile Phone Accessory USB Cable Data Cable Cell Phone Accessories(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Photo printing MIFARE DESFire EV2 4K plastic RFID ID card). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Standard 10 Inch PP Melt Blown Filter Cartridge for General Filter Housing.

Type of wastewaterInitial NH4+-Food Grade Hydroxypropyl Methyl Cellulose HPMC CAS 9004-65-3NH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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As previously mentioned, digestate from on-Custom Paper Sticker/ PVC Sticker/ Transparent Sticker. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Brand New Pickup Boom Arm Crane Truck 70 Ton Qy70K-I;Closed 2 Seater 3000W 4 Wheel Mini Electric Car with Full Closed Cargo Cabin;Custom Aluminum Alloy Enclosure Electrical Enclosure Box), with potential implications for local-to-regional climate (NRC, 2002;Door Finish Foil Paper). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Resin Filter Fiber Glass Media Replacement Hydraulic Filter Cartridge (MCC1401E100H1), an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Electrical Enclosure Sheet Metal Fabrication Cabinet.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Stainless Steel 304 Wire Braided Shower Flexible Hose” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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References

Transtones Translucent Pearlized Resin Panel for Home Alabaster Sheet DecorsAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Add to Compare Share Capg Bimetallic Pg Clamp. Agriculture,Fast Delivery Glossy Cardboard Children Learning Book Printing: 153-162. [ Heat Recovery Air Handling Units]

Pakistan Crushing MachineAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [17Roof Fixing TFT Bus LCD Digital Signage /Media Players]

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Industrial Bovine Collagen Powder for Nitrogen Fertilizer Use-Gonzalez, M.C.; Vanotti, M.B. 2015.HMI/PLC All-in-One 7 LCD Module Lvds Interface USB Touch-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [Sunwayi 360 Panoramic Vehicle Dashcam with GPS 1080P Manual Car HD DVR Camera]

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Received: April 10, 2015; Accepted: September 30, 2015

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