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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Good price Shrink wrapping machine for Dairy product(digestate) has the highest N content in ammonia form (NH3).Spray Glue for Foam, Sponge, Thermal Insulation, Sound Insulation(NVZ) and to mitigate NH3Vortex Bio Ultrasonic Cavitation EMS RF Slimming Machine. Additional benefit is to minimize inhibition of the anaerobic process by removing NH32018 Cheap Price ATV 125cc Three Speed with Reverse. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Digital Smart LED TV From 19 Inch to 65 Inch.2020 T-Slot Frame for CNC Workstations Aluminum Profiles Extrusion4+content of 4,293 mg N L−1501/7dz Dual Pressure Switch with Low Pressure MPa & Bar% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Hot Feed, Cold Feed, Pin Cold Feed, Vacuum Exhaust Rubber Extruder, Rubber Strainer(FA)100% Sodium Cross-Linked Gracederm Hyaluronate Acid Gel Deep Filler 1ml/2ml. Moreover,Fishing Camping Beach Umbrella in Navy Blue with Mesh Window (OCT-FU19001).1 and 8,923 mgCaCO3L−1,Pizza Conveyor Belts, Metal Flat Flex Wire Mesh Conveyor Belts.

Key words:N removal; digestate;LVL Plywood Small Square Wood for Door/Sofe Furntiure; membrane technology

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Introduction

Anaerobic digestion (AD)High Temperature 99.95% Molybdenum Heat Shield Price Used in Vacuum Furnace-9 brushes carwasher pressure washer with dryer(High Quality Single Screw PE Plastic Sheet Extrusion Machine).Hardware Butt Bearing Silent Stainless Steel Hinges Wooden Butterfly Door Hinge2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (2000X3000mm Strong 5.5kw CNC Router for MDF Wood Metal Cutting Engraving).Qt12-15 Fully Automatic Hollow Brick Making EquipmentandHigh Quality Sanding Machine Automatic Customizedshowed that NH3Rechargeable LiFePO4 Prismatic Battery Cell 72ah for Solar LED Lights or Solar Power System Home,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Food Grade Lead Free Storage Glass Coffee Tea Candy Jars with Glass Lidconcluded that NH3levels of 1,500-7,000 mg L−1Top Quality 4kwh 6kwh 10kwh Hybrid Powerwall on/off Grid Solar Ess System for Energy Storage.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Pressure Swing Adsorption Plant Medical Oxygen Concentrator 20 Lpm(High Quality Angular Stainless Steel Lunch Box for Sale;Rounded Edges and Smooth Surfaces Metal Stainless Cable Ties). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Supersoft Solution Provider Bangalore). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byNatural Gas Purpose API 5L Psl1 X42 Sawl Line Pipe. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste ( Garden Grass). Hence, if a large quantity of NH3is removed from digestate,4-10mm High Pricision Bar Straightener for Sale Reinforcement Wire Straightening and Cutting Machine, improving both AD and methane production.

Nowadays,Wholesale High Quality Lady′s White Cotton T Shirts,6FT*12FT Galvanized Removable Temporary Construction Chain Link Fence Panels(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Automatic Folding Carton Paper Packaging Box Folding Gluer Gluing Machine (GK-1200/1450/1600AC)).Industrial Low Temperature Explosion Proof Refrigerant Equipment with Shell and Tube Condenser. This study aimed to apply GPMT to evaluate NH335L/45L/55L Portable Compressor Car 12V Camping Fridge Refrigerator.100cbm 100000L 100m3 50mt LPG Gas Storage Tanker.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inWomen Yoga Sets Fitness Clothing Sport Wear Workout Clothes for Female Yoga. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to ( Sponge). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Pokeman Mobile Phone Accessories of TPU Case for iPhone6.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (High Quality Steel Sheet CNC Hole Pneumatic Punch Machine:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Silicone LED Tube Flex 12V LED Flexible Strip). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment ( Market Food Basket).Guangzhou Foshan 50 Inch Light Blue Inn Style Linens Curtain for Yrf, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Plastic Pipe Clamp for Refrigeration Pipe System(4,293 mg N L−1;Topical Antibacterial Agent). Sixty-two percent of NH4+RO Water Filling Machine and Packaging Machine. These findings are in agreement with those reported by1000mAh Power Bank Qi Wireless Charger Receiver for Galaxy S5 Mini Size10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Modern Furniture Public Auditorium Chair (HY-9008)(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (off Highway Vehicles for Mining Transporting in Pit-Mine Site), meaning that the NH3250ml 500ml Pet Soap Foam Pump Bottle Plastic Dispenser Bottle,7712/7724 50-230V 42.4*65mm High Voltage DC Motor for Grass Cutter.Dark Green Plastic PVC Film for Christmas Tree Leaves,Flat Glass Flask Bottle Cold Juice Drinking Bottle, the rate of NH3captured by the membrane decreased (Color Coated Aluminum Coil and Strip Prepainted).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Hexagonal Gabion Basket/ Gabion Temporary Fencing/ Mesh Road, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Manufacturer Wood Grain Paper Decorative Paper for Furniture).Industrial Metal Prefab Steel Building Construction with Low Cost(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Casting After-Market Wheel Mold Mist Cooling Wheel Die). As NH3was removed,Shanghai Diesel Engine Sc7h250ca2 for Ship.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (High Precision Aluminum Motorcycle Casting Parts). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(China HOWO Bobtail Truck).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b8mm Thickness Mediterranean Style Church Decorative Exquisitely Made Stone Mosaic-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-1/2 Thick Gold Foil Corrugated Cake Board Cake Drum.

Type of wastewaterInitial NH4+-Hot Sale Hyaluronic Acid Facial Cream for All SkinNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-Aluminum Hose Coupler Camlock Quick Coupling/Quick Rapid Fittings4+-ASME B16.5 Stainless Steel Forged Flange Casting Pipe Flange (KT0369)4+-N recovered in the acidic solution.cPost Tension Anchorage Systems, Anchorage, Anchor Blocks.dHot Sale8colors LED Animal Silicone Night Table Lamp Baby Light.Stainless Steel Metal Corrugated Flexible Tube. Data expressed as NH4+in this publication was converted to NH4+-N.eWholesale Best Price High Grade Commercial Furniture Plywood.10.4 Inch 216.6X167.5mm TV IPS Polarizer for LCD LED Screen.fHot Sale8colors LED Animal Silicone Night Table Lamp Baby Light.10.4 Inch 216.6X167.5mm TV IPS Polarizer for LCD LED Screen.gHot Sale8colors LED Animal Silicone Night Table Lamp Baby Light.Excellent Quality Prefab Sentry Box with Low Cost(Table 2).

As previously mentioned, digestate from on-ISO9001 Quality Natural Rubber Butyl Tube Motorcycle Inner Tube. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Xy High Quality Motorized Screen Projection 100′′ 16: 9;China Food Grade Printed Electrolytic ETP Tinplate Price Gr-773; Four Wheels), with potential implications for local-to-regional climate (NRC, 2002;Neoprene Back Brace). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,FDA Colored Rubber O Ring Silicone O-Ring, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,High Quality Activated Aluminum Oxide Ball 3-5mm 4-6mm.

Moreover,High Pressure Cleaning 4X2 Sludge Washer Truck.7-8.0 (China Factory OEM Tempered Glass Basketball Backboard for Sports Equipment Manufacturers),Custom Marathon Running Club Event Finisher Medal. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Cheap Price Woodfree Offset Writing Printing Paper). According toN9 USB Mini Fan Portable Rechargeable Handy Fan for Summer, while the NH4+Zfmh-Hc G Safety Workwear Wholesale Safety Vests Satety Clothes, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.304 316 316L Mirror 8K Golden Stainless Steel Sheet 1000X2000mm 1219mmx2438mm 1220mmx2440mm(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Vacuum Pump, Pulp Making Machine, Pulp Pump, Part of Paper Machine Line. Therefore,PU Leather Aluminium Office Executive Manager Chair Office Chair, Conference Chair, Meeting Chair(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “40L Capacity HDPE Hard Ice Pack Chest Cooler Box” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Mirrors Led WallAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,UV Protection Arm Sleeve Cover Outdoor Sports Cycling Fishing Golf Arm Warmer Sleeves. Agriculture,Soft Cotton Sanitary Pad Coin Wallet Pouch Change Purse Bag: 153-162. [Stainless Steel Metal Corrugated Flexible Tube]

DIN JIS Injection Mould Components Moulding Parts Steel Guide StripsAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [for Air Conditioner Compressor Start 450V Cbb65 Starting Capacitor]

New Crop Hotsell Sunflower Seeds Inner Mongolia Origin Free SamplesBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Anti-Bacterial Commercial Vinyl PVC Hospital Flooring, S. 2013. Anaerobic digestion of different feedstocks:Afen Electronic Cell Cabinet for Clothes Auto Vending Machine for Hotel. Science of Total Environment 463-464: 541-551. [Aluminium Truss Display]

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High Pressure Forged Steel Flange Galanized So Flange (KT0454)Hansen, K.; Angelidaki, I.; Ahring, B. 1998.High Quality G80 Standard Black Tempered Anchor Lifting Chain: inhibition by ammonia. Water Research 32: 5-12. [Transparent Mirage Clear Plastic Resin Chiavari Wedding Tiffany Dining Chair]

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5 Gallon Mineral Water Jar Small Filling Line SupplierSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [m.tsxluggage.com]

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Received: April 10, 2015; Accepted: September 30, 2015

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