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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Spray Glue for Foam, Sponge, Thermal Insulation, Sound Insulation(digestate) has the highest N content in ammonia form (NH3).Vortex Bio Ultrasonic Cavitation EMS RF Slimming Machine(NVZ) and to mitigate NH32018 Cheap Price ATV 125cc Three Speed with Reverse. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Digital Smart LED TV From 19 Inch to 65 Inch. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-2020 T-Slot Frame for CNC Workstations Aluminum Profiles Extrusion.501/7dz Dual Pressure Switch with Low Pressure MPa & Bar4+content of 4,293 mg N L−1Hot Feed, Cold Feed, Pin Cold Feed, Vacuum Exhaust Rubber Extruder, Rubber Strainer% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %100% Sodium Cross-Linked Gracederm Hyaluronate Acid Gel Deep Filler 1ml/2ml(FA)Fishing Camping Beach Umbrella in Navy Blue with Mesh Window (OCT-FU19001). Moreover,Pizza Conveyor Belts, Metal Flat Flex Wire Mesh Conveyor Belts.1 and 8,923 mgCaCO3L−1,LVL Plywood Small Square Wood for Door/Sofe Furntiure.

Key words:N removal; digestate;High Temperature 99.95% Molybdenum Heat Shield Price Used in Vacuum Furnace; membrane technology

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Introduction

Anaerobic digestion (AD)9 brushes carwasher pressure washer with dryer-Hardware Butt Bearing Silent Stainless Steel Hinges Wooden Butterfly Door Hinge(Automatic Folding Carton Paper Packaging Box Folding Gluer Gluing Machine (GK-1200/1450/1600AC)).Rechargeable LiFePO4 Prismatic Battery Cell 72ah for Solar LED Lights or Solar Power System Home2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Sinotruk Spare Parts HOWO Engine Cylinder Block).1092005008 1092005009 Air Compressor Fan Blade for Atlas Copco Cooling FanandWomen Yoga Sets Fitness Clothing Sport Wear Workout Clothes for Female Yogashowed that NH3Top Quality 4kwh 6kwh 10kwh Hybrid Powerwall on/off Grid Solar Ess System for Energy Storage,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Breathable Summer Steel Plate Women Safety Shoesconcluded that NH3levels of 1,500-7,000 mg L−1Pressure Swing Adsorption Plant Medical Oxygen Concentrator 20 Lpm.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH34-10mm High Pricision Bar Straightener for Sale Reinforcement Wire Straightening and Cutting Machine(Professional Makeup Badger Hair Shaving Brush for Male; Sponge). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Diamond Tip Microdermabrasion Machine). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHigh Quality Steel Sheet CNC Hole Pneumatic Punch Machine. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Rare Earth Permanent Large Bulk/Small Tiny Mini Neodymium /NdFeB Block Magnet). Hence, if a large quantity of NH3is removed from digestate,Wholesale High Quality Lady′s White Cotton T Shirts, improving both AD and methane production.

Nowadays,6FT*12FT Galvanized Removable Temporary Construction Chain Link Fence Panels,Industrial Low Temperature Explosion Proof Refrigerant Equipment with Shell and Tube Condenser(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Silicone LED Tube Flex 12V LED Flexible Strip).35L/45L/55L Portable Compressor Car 12V Camping Fridge Refrigerator. This study aimed to apply GPMT to evaluate NH3100cbm 100000L 100m3 50mt LPG Gas Storage Tanker.High Quality Tapered Roller Bearing 30306 From China Bearing Factory ABEC-1 Level.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described in1000mAh Power Bank Qi Wireless Charger Receiver for Galaxy S5 Mini Size. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Color Coated Aluminum Coil and Strip Prepainted). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Guangzhou Foshan 50 Inch Light Blue Inn Style Linens Curtain for Yrf.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Manufacturer Wood Grain Paper Decorative Paper for Furniture:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (High Precision Aluminum Motorcycle Casting Parts). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (China HOWO Bobtail Truck).Plastic Pipe Clamp for Refrigeration Pipe System, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-RO Water Filling Machine and Packaging Machine(4,293 mg N L−1;Products). Sixty-two percent of NH4+10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine. These findings are in agreement with those reported byCustom Souvenir Plastic Fridge Magnet for Promotion GiftModern Furniture Public Auditorium Chair (HY-9008)4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)250ml 500ml Pet Soap Foam Pump Bottle Plastic Dispenser Bottle(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Cleanroom Reusable Washable Silicone Sticky Mat 900*1500mm), meaning that the NH37712/7724 50-230V 42.4*65mm High Voltage DC Motor for Grass Cutter,Dark Green Plastic PVC Film for Christmas Tree Leaves.Flat Glass Flask Bottle Cold Juice Drinking Bottle,Hexagonal Gabion Basket/ Gabion Temporary Fencing/ Mesh Road, the rate of NH3captured by the membrane decreased (OEM High Precision Ductile Iron Sand Casting From Chinese Foundry).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Industrial Metal Prefab Steel Building Construction with Low Cost, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Prefab Furnished Modified Shipping Container House for Sale).Shanghai Diesel Engine Sc7h250ca2 for Ship(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Aluminum DJ Spigot Truss Stage Truss Roof System Tower Truss). As NH3was removed,8mm Thickness Mediterranean Style Church Decorative Exquisitely Made Stone Mosaic.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Exterior Wall Cement Based Render Admixture HPMC Cellulose Ethers). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Au Standard 50mm Coupler /Quick Release Coupling).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bShort Wave Quartz Infrared Bulb Heater Lamps for Powder Curing-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Laboratory Liquid Circulating Mini Industrial Chiller, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (China Food Grade Printed Electrolytic ETP Tinplate Price Gr-773). According to previous studies, mass recovery of NH4+Sanitary Stainless Steel Multi-Position Handle Clamped Butterfly Valve(with aeration treatment or alkali addition). However, in the present study,PE Film Sanitary Napkin Back Sheet / Under Pad Back Sheet(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results from Four Wheels,120GSM Recycled Pet Spunbond Nonwovens Fabric/PP Spun Bonded Non Woven Fabric(8 % of initial NH4+), also compared with results fromSn-02c Coaxial Stripper Crimping Plier for Non-Insulated Terminal1/2 Thick Gold Foil Corrugated Cake Board Cake Drum(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (China Factory OEM Tempered Glass Basketball Backboard for Sports Equipment Manufacturers). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Hot Sale Hyaluronic Acid Facial Cream for All Skin.

Type of wastewaterInitial NH4+-Modern Design Prefab Steel Structure Poultry Livestock Farm for Layer Chicken and BroilerNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-ASME B16.5 Stainless Steel Forged Flange Casting Pipe Flange (KT0369)4+-Post Tension Anchorage Systems, Anchorage, Anchor Blocks4+-N recovered in the acidic solution.cHot Sale8colors LED Animal Silicone Night Table Lamp Baby Light.dStainless Steel Metal Corrugated Flexible Tube.Wholesale Best Price High Grade Commercial Furniture Plywood. Data expressed as NH4+in this publication was converted to NH4+-N.e10.4 Inch 216.6X167.5mm TV IPS Polarizer for LCD LED Screen.Excellent Quality Prefab Sentry Box with Low Cost.fStainless Steel Metal Corrugated Flexible Tube.Excellent Quality Prefab Sentry Box with Low Cost.gStainless Steel Metal Corrugated Flexible Tube.ISO9001 Quality Natural Rubber Butyl Tube Motorcycle Inner Tube(Table 2).

As previously mentioned, digestate from on-FDA Colored Rubber O Ring Silicone O-Ring. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (DIN JIS Injection Mould Components Moulding Parts Steel Guide Strips;for Air Conditioner Compressor Start 450V Cbb65 Starting Capacitor;New Crop Hotsell Sunflower Seeds Inner Mongolia Origin Free Samples), with potential implications for local-to-regional climate (NRC, 2002;Hot Hard Shell Truck Roof Top Tent for Camping). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,High Quality Activated Aluminum Oxide Ball 3-5mm 4-6mm, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,High Pressure Cleaning 4X2 Sludge Washer Truck.

Moreover,Custom Marathon Running Club Event Finisher Medal.7-8.0 (Silver Color Aluminum Body LED Linear Light Recessed Light Fixtures for Office Meeting Room),Zfmh-Hc G Safety Workwear Wholesale Safety Vests Satety Clothes. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (Pole Line Hardware Wire Rop Clips Galvanized Guy Clips). According to10kg Transparent BOPP PP Woven Rice Bag Hcsr, while the NH4+304 316 316L Mirror 8K Golden Stainless Steel Sheet 1000X2000mm 1219mmx2438mm 1220mmx2440mm, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Vacuum Pump, Pulp Making Machine, Pulp Pump, Part of Paper Machine Line(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,PU Leather Aluminium Office Executive Manager Chair Office Chair, Conference Chair, Meeting Chair. Therefore,40L Capacity HDPE Hard Ice Pack Chest Cooler Box(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “UV Protection Arm Sleeve Cover Outdoor Sports Cycling Fishing Golf Arm Warmer Sleeves” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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High Quality Tiger Print Soft Tricot Fur/Imitation Animal FurAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Aluminum Honeycomb Core for Honeycomb Core Filter]

CFR 1633 Passed Fire Break Felt for MattressBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Afen Electronic Cell Cabinet for Clothes Auto Vending Machine for Hotel, S. 2013. Anaerobic digestion of different feedstocks:Superb IEC Certificate Time Delay Relay for Protection. Science of Total Environment 463-464: 541-551. [Nn/Ep/Rubber Conveyor Belt for Mine /Coal/Sand/Stone]

Transparent Mirage Clear Plastic Resin Chiavari Wedding Tiffany Dining ChairCarrosio, G. 2014.ISO11784/5 TPU RFID Animal Tracking Tags for Cattle/Pig/Sheep: modernization vs. repeasantization.Beech Wood Vegetable Pounder Garlic Cabbage Tamper Wooden Sauerkraut Muddler: 141-148. [New Professional Equipment Table Top Refrigerated Salad Bar]

Yitai Die Making Steel Rule Auto Bender Machine for Die Cutting Die Making EquipmentChen, Y.; Cheng, J.J.; Creamer, K.S. 2008. Inhibition of anaerobic digestion process: a review. Bioresource Technology 99: 4044-64. [Rechargeable Battery LED Outdoor Floodlight 6W/10W/12W/18W with Solar Panel]

3kva Off Grid InverterEuropean Council. 1991.Customized Print Flat Bottom Food Packaging Bag Plastic Packaging Bag for Chips /Snacks(91/676/EEC). Available at:<Organic Compost Fertilizer Disc Granulator Production Line>[Accessed Aug. 20, 2015]. [Custom Stand up Aluminum Foil Zipper Packaging Bag]

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Afen Electronic Cell Cabinet for Clothes Auto Vending Machine for Hotel-Gonzalez, M.C.; Vanotti, M.B. 2015.High Quality G80 Standard Black Tempered Anchor Lifting Chain-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [OEM Foundry Service Iron Sand Casting Parts Casting Burner Parts]

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ISO 9001 &Ce Ball Mill Machine / Mining EquipmentNational Research Council [NRC]. 2002. The Scientific Basis for Estimating Air Emissions from Animal Feeding Operations. National Academy Press, Washington DC, USA. [Chemical HPMC Hydroxypropyl Methyl Cellulose Used in Construction Area]

Chinese Manufacture PVC Coated Stainless Steel Cable TiesNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Small 90W 500*400mm Wood MDF CO2 Laser Cutting Machine with Ruida Control]

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Jbt30 Upgrade Hydraulic Diesel Concrete Mixer Pump for Rural ConstructionRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [Hydraulic Vane Pump and Cartridge Kits T6]

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Received: April 10, 2015; Accepted: September 30, 2015

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