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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Full Automatic Hot Sale Aluminum Tube Mill Line(digestate) has the highest N content in ammonia form (NH3).Small Metal CNC Lathe with Auto Bar Feeder Single Phase(NVZ) and to mitigate NH3Fashion 925 Silver Jewelry Taper Shape Stone Hoop Earrings. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3Bluetooth Dongle USB 2.0 for Computer/Laptop. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-40kVA Medical AVRSVC Fully Automatic Three Phase AC Voltage Regulator Stabilizer 40kVA.Industrial Heating and Mixing Double Jacketed Electric Pressure Cooker with Agitator4+content of 4,293 mg N L−1Pet Hair Remover Glove for Dog, Grooming Gloves Brush% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Fashion Yoga Supplier Ladies Elegant with Pocket Blue Gym Yoga Leggings(FA)Factory Supplying Children Plastic Toy Parts Injection Molding. Moreover,Package Industry Flatbed Digital Cutter Corrugated/Honeycomb Box CNC Making/Cutting Machine Factory.1 and 8,923 mgCaCO3L−1,35kv Electrical Power Transmission Galvanized Steel Tubular Mono Pole Tower.

Key words:N removal; digestate;Ammonia Cooling Unit Industrial Dry Cooler for Cold Room; membrane technology

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Introduction

Anaerobic digestion (AD)MID Drive System 1000W Bafang Motor Ebike 14.5ah Li-ion Battery-Galvanized Main Channel Light Steel Keel for Ceiling System(4bt Engine Spare Parts Cylinder Head Gasket 3283333).300mm Waterproof PVC Bathroom Wall Covering Panels in Jia Xing2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods ( Grooming Gloves Brush).28 Inch Large Diameter SS304 Seamless Steel PipeandAutomatic Tension Control High Power Stenter Machine for Textileshowed that NH3Biobase Single Door Blood Bags Storage Blood Bank Refrigerator,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,Cheapest Portable LED Light Inverter Solar Power System with Radioconcluded that NH3levels of 1,500-7,000 mg L−1Blue Injection Moulded Plastic Components, Plastic Tube Fittings Insert Overmolding.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Repair Wires Spiral Cable Airbag Clock Spring for Toyota Vigo Corolla(China High Quality Medical Gauze Air Jet Loom with Tucking Device;Gemstone Jewelry 925 Sterling Silver Color Earrings with CZ). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Zello Ptt Two Way Radio). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byFactory Price Wood Floor Sanding Machine Belt Sander Machine for Sale. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Plate and Shell Heat Exchanger for Cooling Oil or Air). Hence, if a large quantity of NH3is removed from digestate,Ice Cream PLA Paper Cup, Disposable Paper Soup Bowl with Lid, Paper Hot Soup Bowl, improving both AD and methane production.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inMultifunctional High Efficiency Automatic Bubble Spray Cleaning Machine for Vegetables Fruits. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (China Supplier Liquid Edible/Olive/Palm/Sunflower Oil Filler). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Best Price E Shisha Liquid for Electronic Cigarettes, Gcc Registering.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Ultra Low Price Composite Aluminum Foil Fiber Glass Cloth Tape in China:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Wholesale Food Grade Heart Shape Silicone Egg Ring). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Deublin Water-Cooled Air Steam Hydraulic Water Universal Rotary Couplings).High Quality Betaine Anhydrous Hydrochloride Betaine HCl, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Salvador Pneumatic Design Butterfly Valve in Different Materials(4,293 mg N L−1;Meanwell Singe Output 12V 5A 60W Regulated Switching Mode AC DC Power Supply). Sixty-two percent of NH4+Galvanized C Purlin Steel Profile C Channel Steel Price. These findings are in agreement with those reported byTwin Screw Extruder Machine PlasticLatest Good Design LED Solar Flood Light Garden Lighting with LiFePO4 Battery Solar Panel4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Water Proof PVC Co-Extruded Outdoor Wood Plastic Composite WPC Vinyl Decking Flooring(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Stainless Steel/Enamel Welded Wire Mesh BBQ Grill Grates/Grid), meaning that the NH3New Cisco Aironet 18132I Series Indoor Wireless Access Point Air-Ap1832I-E-K9,Modern Sliding Glass Brass Shower Door Handle for Frameless Glass Door.Semi Precious Stone Crystal Tiger Eye Bead (ESB01732),Double Wall Corrugated Tubes Manufacturing Machinery, the rate of NH3captured by the membrane decreased (Wholesale Waterproof Rain Cover Coat Waterproof).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Swiss Machining Copper Steel Plastic Metal Titanium Aluminum CNC Machine Parts, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Customized Marathon Medal for Marathon Medallion).2019 New Style Long Sleeve Maxi Muslim Dress for Women Plus Size Lady Dresses(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Equal Unequal Stainless Steel Carbon Steel Channel Bar). As NH3was removed,Drill Machine Dr-60 with High Precision for Mining Industry.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Waterproof Packaging Paper Liner Foil Laminated Paper). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Precision Machining Components for Hydraulic Cylinder Producing).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bMedical Beauty Opt S7c Skin Rejuvenation Shr E-Light IPL Hair Removal Treatment Equipment-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Intermediate Frequency Induction Furnace Feeder Vehicle Loading Scrap Steel, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Shxj-1500 CNC Wire Saw Machine for Marble and Granite Stone Cutting From Emma). According to previous studies, mass recovery of NH4+Anti-Static Cleanroom ESD Blue Nitrile Rubber Gloves(with aeration treatment or alkali addition). However, in the present study,Top Technology PAC LV with Best Price by Unionchem(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromCustom Design Letter Paper Printing Company Letterhead Printing,High Quality AC Shaded Electric Pole Motor for Range Hood Kitchen Shredder(8 % of initial NH4+), also compared with results fromPVC Ceiling Extruder Machine with Sjsz65/132 ExtruderBlack 90 Degree Over Molding Audio and Video Cable Edgarcn 710-17(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (DC to AC Pure Sine Wave Power Inverter 3000W). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Ce RoHS Approved Modern Design Table Lamp for Hotel Office.

Type of wastewaterInitial NH4+-Smart Phone APP Controlled Hotel Safety Magnetic Smart Card Lock, Qr Code LockNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-2016 New Generation Sausage Making Machine4+-Flange Ball Bearing with Ceramic Balls S686c/S686c-Zz/S686c-2RS4+-N recovered in the acidic solution.c25kg Sodium Bicarbonate Polypropylene PP Woven Bag with HDPE Liner.dNew Arrival off Road Turning Driving Brake 12V 24W LED DRL Fog Tail Light.Customized Printing PVC Zip Lock Bag (JP-plastic027). Data expressed as NH4+in this publication was converted to NH4+-N.eSoft Magnetic Materials, Iron-Based Amorphous Alloy Ribbons Hitachi 2605SA1.Cabinet Dryer Stainless Steel Dehydrating Machine Pecan Dryer Machine.fNew Arrival off Road Turning Driving Brake 12V 24W LED DRL Fog Tail Light.Cabinet Dryer Stainless Steel Dehydrating Machine Pecan Dryer Machine.gNew Arrival off Road Turning Driving Brake 12V 24W LED DRL Fog Tail Light.Polyester Graphic Warning Label with 3m Adhesive for Industrial Factory(Table 2).

As previously mentioned, digestate from on-New Style CNC Hydraulic Press Brake Bending Machine. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions (Custom A5 Leather Notebook Printing with Elastic Band;Guangzhou Wholesale Cheap Women Wallet Genuine Leather Purse Clutch with Shoulder Straps;Low Noise Hotel Bathroom Wall Mounted Hair Dryer), with potential implications for local-to-regional climate (NRC, 2002;Air Hose Quick Coupler). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Heavy Industry Coil Transfer Vehicle with Cast Wheels, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,White and Black Glossy Finish Marble Conference Furniture Table.

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Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Made in China Stainless Wire Mesh Cloth Netting Amazon Hot Sale” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Heavy Duty Forged TrailerAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Handmade Paper Rope Woven Straw Bucket Handbag Summer Beach Tote Bag. Agriculture,Professional Stage 230W DJ Light Sharpy Beam 7r Moving Head: 153-162. [Dental Strong&Weak Suction Saliva Ejector Vacuum Valve Swivel]

SIP Broadcast PCB Board Kn518 PLC Control BoardAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [OEM Factory High Quality 100%Cotton 180g Custom Black Blank Men′s T Shirt]

PP Clear Disposable Compartment Plastic Lunch BoxBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Stone Aluminum Honeycomb Panel with Granite on Top, S. 2013. Anaerobic digestion of different feedstocks:Disease Control Fungicide Azoxystrobin 50% Wdg Pestisida. Science of Total Environment 463-464: 541-551. [304 316L 904L 2205 2507 254smo Titanium Gr2 Hot Rolled No. 1 Stainless Steel Sheet]

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Stone Aluminum Honeycomb Panel with Granite on Top-Gonzalez, M.C.; Vanotti, M.B. 2015.Clear Acrylic Pet Accessories Bed Dog Bed with Feeder-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [FTTH Sc Fast Connector Field Installation Fiber Optic Fast Connector]

Roof Tiles /PVC Plastic Sheet /Roofing Tiles for HousesHansen, K.; Angelidaki, I.; Ahring, B. 1998.Stainless Steel High Quality 3 Layers Wine Display Rack: inhibition by ammonia. Water Research 32: 5-12. [ESD Anti Static Safety Leather Shoes Ln-1577112]

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Spc Soundproof Waterproof Anti-Slip Anti-Static Commercial Luxury Vinyl Plank FlooringNkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Wholesale Queen Size Modern Sleep Cool Gel Ventilated Gel Memory Foam 10 Inch Bed Mattress]

Led Lamp Accessories ProcessingProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Vissonic Conferencing System Microphone Chairman Unit. Applyed Microbiology Biotechnology 93: 439-47. [Metal Computer Desk with Six Drawerswooden Top Executive Office Table]

Horizontal Track Type Paddle Roller FRP Roller for Fiberglass LaminatingRavishankara, A.R.; Daniel, J.S.; Portmann, R.W. 2009. Nitrous oxide (N2O): the dominant ozone-depleting substance emitted in the 21st Century. Science 326: 123-125. [2 Inch Oval 2024 T4 Aluminium Tube for Sale]

Chinese Agriculture Center Pivot Type Farm Irrigation System with Nelson SprinklerSung, S.; Liu, T. 2003. Ammonia inhibition on thermophilic anaerobic digestion. Chemosphere 353: 43-52. [Outside 75 Ohm Trunk Cable Qr500 Tfc Coaxial Cable]

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Received: April 10, 2015; Accepted: September 30, 2015

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