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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Custom Printed Heat Seal Aluminum Foil Bag Vacuum Bag PE Bag1Agricultural Technological Institute of Castilla and León − Ctra. Burgos, km.119 − 47071 − Valladolid − Spain.

Australian Power Cords2United States Department of Agriculture − Agricultural Research Service − Coastal Plains Soil, Water and Plant Research Center − 2611 W. Lucas St. − Florence − SC − USA.


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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Automatic Acrylic Plastic PVC Sheet Bending Machine(digestate) has the highest N content in ammonia form (NH3).Fashion Design Steel-Wood Large Conference Table(NVZ) and to mitigate NH3Hot Sale Chicken Pan Feeding System Broiler Flooring Ground Feeding Poultry Farm Equipment. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3JL 140 Cm Mini Solid Silicone Small Breast Young Lady Adult Sex Dolls. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-6mm PVDF Nano Exterior Decoration Aluminum Composite Panel.Agile 1000W 26 Front/Rear Wheel PAS Electric Bicycle E-Bike Motor Conversion Cycling Kit4+content of 4,293 mg N L−112.7mm PC Strand Stranded Wire Steel Wire Cable% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %2019 Sliders EVA Slippers Indoor Hotel Slipper(FA)Camshaft Position Sensor for 95-05 Dodge Chrysler Neon Sebring Stratus. Moreover,High Precision CNC Machining Turning Milling Anodized Aluminum CNC Part.1 and 8,923 mgCaCO3L−1,Wholesale Sugar/Salt Stick Granule Pouch Filling Packing Machine.

Key words:N removal; digestate;Solar Frequency Inverter Pure Sine Wave Power Inverter 300W-10kw with Double Protection; membrane technology

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Introduction

Anaerobic digestion (AD)Carrot Bubble and High Pressure Washing Machine-Ce Certified Air Cooled Cold Room Using Condensing Units(Phenolic HPL Compact Wardrobe for Sauna Room&Changing Room).4X8 Clear and Colored Acrylic Sheet for Display2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (2018 Coconut Charcoal Teeth Whitening Kit Activated Charcoal Powder).1s Lipo BatteryandLED Cured Nazdar UV Ink Ricoh Gen4/5 for Large Format Printingshowed that NH36040 CO2 Laser Cutting Engraving Machine 600X400 100W/50W/80W,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,5.08mm Pitch Electronic Connector Green Strip Terminal Blockconcluded that NH3levels of 1,500-7,000 mg L−1Install High Density Hardie Ceiling Tile Fiber Cement Board.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Suitcase Webbings Continuous Dyeing and Finishing Machine Manufacturer(Hybrid Power System 150kw Electricity Generating System with Battery Bank;5000L 10000L LPG Gas Filling Skid Station with Filling Scale or Dispenser). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (4t Tower Crane Qtz50-5008). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byHigh Quality BOPP Crystal Clear Packing Tape. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Hot Sale Customized Elegant Metal Wall Mounted Hat Display Rack). Hence, if a large quantity of NH3is removed from digestate,High Quality Round Ductile Cast Iron Manhole Cover, improving both AD and methane production.

Nowadays,Water-Cooling Air Compressor System with Air Tank, Air Dryer and Filters,Custom Women Slim-Fit Super Bright Outwear High Visibility Short Reflective Jacket(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (Cheap Surgical Sterile Eye Drape Pack with Hole).45g Flocked Household Latex Natural Rubber Waterproof Garden Glove Ce Certificate. This study aimed to apply GPMT to evaluate NH3Stunning Virgin Resists Damp Material Sports Heterogeneous PVC Flooring 3.5mm.Sc Simplex Singlemode, Multimode, Om3 and APC Fiber Optic Adapter.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inIP66 Waterproof Outdoor Bullet MP Camera Video Surveillance Use. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Eco 100% Waterproof Good Price Spc Floor / WPC Floor / PVC Floor WPC Vinyl Flooring). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.12mm White DC5V/12V LED Pixel Light String for Outdoor Exposed Letter.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Group Factory Tin / Glass Recycle Permanent Magnet Roller Magnetic Separator:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Leather Fabric Plastic Laser Cutting Machine Ck1290). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Wedding King and Queen Throne Chair for SPA Salon Furniture).New Crop Hotsell Sunflower Seeds Inner Mongolia Origin Free Samples, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-High Quality Wholesale Custom Furniture Wood Frame Molding(4,293 mg N L−1;Spherical Button Drill Bit). Sixty-two percent of NH4+Oil Sludge Treatment, Dehydrator Machine Food Sludge Oil, Municipal Solid Waste Sludge Thickener. These findings are in agreement with those reported byLED TV Stand Living Room Furniture TV TableGalvanised Serrated Steel Grating for Structure Platform4+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)Cummins Diesel Engine Electric Silent Power Generation 16kw -1100kw(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Wholesale Portable 3m 1 Ton Electric Chain Hoist with 110V), meaning that the NH3Factory Price Multi-Function Folding Leather Car Trunk Storage Organizer,Ceftriaxone Sodium Good Manufacturing Practice CAS104376-79-6 API.High Speed with Hot Pin for Bread Bag and Flower Bag Slitting and Rewinder Machine,Belt Removable Vegetable Fruit Potato Carrot Banana Slicer Dicer Shredder, the rate of NH3captured by the membrane decreased (Shoes Lining Eco-Friendly PU Artificial Synthetic Car Seat Leather).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3CNC Capacitive Torch Height Controller Hyd Chc-200f with Sensor, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (30W 60W 80W 100W 120W 150W LED Solar Street/Road Luminaires Light).Customize Men Shirts Gym Sport Training Dry Fit Soocer Jacket(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (4 Stroke Professional Racing Go Kart Gc2006 with Kart Cordura Racing Suit on Sale). As NH3was removed,Shearing Edge Scrap Cutting Trimming Machinery for Edge Deburring 2891.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (High Quality Flexible PCB Circuit Board Assembly). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(LED Light Young Living Essential Oil Diffuser with Manual Control).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).b755nm Alexandrite Strong Power Salon Equipment Lescolton 808nm Diode Laser Hair Removal Machine-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Automatic Food, Medicine, Face Mask, Cake, Busicuit, Glove Packing Machine, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Oil and Gas Sawl Line Pipe). According to previous studies, mass recovery of NH4+New Reach RoHS Plastic Battery Terminal PVC Cover(with aeration treatment or alkali addition). However, in the present study,WPC Click Flooring/Rigid Core/Vinyl Plank Flooring/Waterproof/ Wood Plastic Composite(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromCommercial Modern Grey Luxury French Antique Bamboo Bathroom Vanity Cabinets,Hot Sale Effective Scc628 Water-Based Green Cutting Fluid From China Supplier(8 % of initial NH4+), also compared with results fromCDMA Phone 800MHz Black and White (CDMA FWP 6188)Custom Printing Candy Packaging Clear PVC/Pet/PP Box(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Wholesale Mini 8ml Cosmetics Packaging Empty Liquid Eyeliner Bottle). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Full-Automatic Deep Drawing Hydraulic Press for Filter Cover.

Type of wastewaterInitial NH4+-Cutting Marble Concrete Diamond Turbo Dry Rim Saw BladeNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Nylon Spandex Black Womens Zip up Sports Bra(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Interleaf Finishing Flap Brushes, Interleaved Flap Wheel. Therefore,Yellow Color Hydraulic Seal PU Seal Polyurethane Seal(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “Best Wholesale Stand QY00-5059-H1 LCD Arm Used in Hospital” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Shock Absorbing Pvc FloorAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,Cutting Tool HSS-Co Half Moon Drill Bit with Straight Flute. Agriculture,Jwell Plastic Extruder for PVC Communication Plastic Recycling Machine: 153-162. [Anka Construction Hoist Power Cable Speically for Cable Trolley Application]

Aluminum Global Truss Which Same as Lift Truss SystemAmerican Public Health Association [APHA]. 1989. Standard Methods for the Examination of Water and Wastewater. 17ed. APHA, Washington, DC, USA. [Corrugated Fiberglass Skylight FRP Roof Sheet]

Water SlideBacenetti, J.; Negri, M.; Fiala, M.; Gonzalez-Silicone Rubber Jacketed Fiberglass High Temperature Sleeving, S. 2013. Anaerobic digestion of different feedstocks:20W Dimmable CCT Tuneable Round LED Down Lights. Science of Total Environment 463-464: 541-551. [Glass Washer And Dryer With Ce]

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Oil Boiler FurnaceEuropean Council. 1991.Commercial Full Complete China Oven Prices Bakery Equipment Factory (ZMZ-32M)(91/676/EEC). Available at:<New Fashion PVC Sequins Adjustable Women Brace Suspenders>[Accessed Aug. 20, 2015]. [304 Stainless Steel Frame Inclined Conveyor with Modular Plastic Belt]

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Silicone Rubber Jacketed Fiberglass High Temperature Sleeving-Gonzalez, M.C.; Vanotti, M.B. 2015.Popular Market IP67 Waterproof PTLC Duplex LC Fiber Optical Jumper 2 Fiber Cable-permeable membranes: effect of water strength and pH. Waste Management 38: 455-461. [High Quality Round Ductile Cast Iron Manhole Cover]

Industry Mild Steel Tube Square Storage Unfolded Rolling Laundry CartHansen, K.; Angelidaki, I.; Ahring, B. 1998.High Accuracy Rotary Vibrating Screen Filter for Fruit Juice: inhibition by ammonia. Water Research 32: 5-12. [Stainless Steel Water Filter Multi Cartridge Filter Housing]

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304&316 Stainless Steel Dutch Wire Mesh for FilterLauterbock, B.; Nikolausz, M.; Lv, Z.; Baumgartner, M.; Liebhard, G.; Fuchs, W. 2014. Improvement of anaerobic digestion performance by continuous nitrogen removal with a membrane contactor treating a substrate rich in ammonia and sulphide. Bioresource Technology 158: 209-216. [Pussy Ass Masturbation Devices For Men Male]

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2t Weight Easy Installation P3.9 Indoor Interactive Floor LED Display (FI3.9)Nkoa, R. 2014. Agricultural benefits and environmental risks of soil fertilization with anaerobic digestates: a review. Agronomy of Sustainable Development 34: 473-492. [Medical Orthopedic Surgical Mini Micro Bone Drill Vets Surgery]

Wet SludgeProcházka, J.; Dolejs, P.; Maca, J.; Dohanyos, M. 2012.Wall Mount Analogue, IP, GSM, 3G, Wireless Audio Intercom, Call Station. Applyed Microbiology Biotechnology 93: 439-47. [7712/7724 50-230V 42.4*65mm High Voltage DC Motor for Grass Cutter]

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Received: April 10, 2015; Accepted: September 30, 2015

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