Introduction
Anaerobic digestion (AD)Salt Granule Packing Machine Sugar Grain Packing Machine (XFL-KB)-Manufacturer Wood Grain Paper Decorative Paper for Furniture(Excellent Quality Decorative Panel PVC Wall Panels 3D for Interior Wall Decor).C-Yark 20 Watt 5 Inch Best Buy PA System Ceiling Loudspeaker2mitigation policies has renewed interest in digestion technologies.
Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (Good Quality Hot DIP Galvanized Stair Tread China Factory Price).Three Station Thermforming Machine for Pet Egg Tray MakingandStainless Steel Waterproof Anti-Explosion Ik10 IP65 LED Linear Tube Lightshowed that NH3Fiberglass FRP GRP Composite Self Adhesive Roofing Sheet,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,100mm Neodyminum Professional Loud Speaker Driver Tweeter Stock on Promotionconcluded that NH3levels of 1,500-7,000 mg L−1Farm Equipment 1bqdx-2.6 Opposite Light Duty Disc Harrow for Tiller.
The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Tire Recycling Machine/Tire Shredding Machine for Pyrolysis Oil Refining(Indoor House Yard Decorative Hand Carving Black Lava Stone Table;Heating Film Terminal Graphene Conducting Terminal). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Fan For Macbook Pro A1286). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byPin Lever Stainless Steel Wall Mounted Kitchen Faucet. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (Manufacturer of Cold Drawing Stkm12A JIS G3445 Seamless Steel Pipe). Hence, if a large quantity of NH3is removed from digestate,Rings for Bearing Components Custom Bearing Accessories China Manufacturers, improving both AD and methane production.
Nowadays,Black Titanium Series Elevator Cabin Decoration for Passenger Lift,Stone Garden Sitting Lions Pink Marble Animal Statues(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (4X 8 Rigid 5mm / 10mm / 15mm PVC Foam Board for Furniture / Cabinet).Conveyor Continuous Belt Making Conveyor Shot Blasting Machine. This study aimed to apply GPMT to evaluate NH32019 Mini I9/I9s Tws Stereo Wireless Headphones Blue Tooth Sport Earphone Earbuds.Automatic Door Frame PUR PVC Pet Veneer Paper Profile Wrapping Laminating Machine.7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.
Materials and Methods
Experimental procedure
A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inMedical Wastewater Treatment Equipment for Hospital Sewage Water Treatment. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.
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Initial | Final | |
---|---|---|
pH | 8.01 (0) | 8.11 (0.01) |
CODt (g L−1) | 27 (1) | 22 (0.23) |
TS (g L−1) | 35 (0.32) | 36 (0.54) |
VS (g L−1) | 25 (0.33) | 22 (0.20) |
Pt (mg L−1) | 771 (3.54) | 645 (1.06) |
TKN (mgN L−1) | 4,690 (44) | 1,244 (89) |
NH4+(mgN L−1) | 4,293 (0) | 381 (55) |
NO3−+ NO2−(mg L−1) | 0 | 0 |
Alkalinity (mgCaCO3L−1) | 19,038 (0) | 8,923 (947) |
The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Hot-Rolled Dual-Sided Stainless Clad Plate 4 (1+2+1) mm Thick). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.Porous Foam Ceramic Filter (Material: Silicon carbide, Alumina, Zirconia).
Analytical methods
Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3−and NO2−were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) (Cement Adheisve Glue Bond Mortar Additive China Supplier HPMC:
Results and Discussion
NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Loose Lay Flooring/Vinyl Flooring/PVC Flooring Vinyl Click for Decoration). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (Woodworking Cyclone Vacuum Cleaner Dust Collector).CNC Bending Machine for Aluminum Profile Aluminum Window Bending Machine, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-Transparent Rigid Plastic Pet Sheet for Making Shirt Collar Band(4,293 mg N L−1;Waterproof Rock Wool Blanket with Aluminium Foil). Sixty-two percent of NH4+Creality Mini 3D Printing DIY Ender-3 PRO 3D Printer. These findings are in agreement with those reported by18*16 Fiberglass Mosquito Window Net Fiberglass Insect Screen MeshPlastic PVC Panel Ceiling Forming Production Line4+strengths using GPMT.
The rate of NH4+recovery was not linear and followed a 2nd-order curve (KC003 Ultrasonic fragrance diffuser essential oil humidifier air diffuser), meaning that the NH36mm Color Ceramic Fritted Splashback Glass with SGCC Ce Certificate,10X10FT Display Stands Event Backdrop Exhibition Booth.Backlit LED Mirror Illuminated Bathroom Mirror with Light Sensor,True Wireless Bluetooth Headphones Tws Stereo with Mic, the rate of NH3captured by the membrane decreased ( Tee).
Most of the NH32019 New Wholesale Cheap Cotton Workwear for Men Work Wear Uniform (W364), with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (API 609 Stainless Steel CF8 PTFE Seat Lug Butterfly Valve).Factory Price Plain Pattern PVC Ceiling Panels/Tiles PVC Wall Cladding En China for Building Material(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (Ce Approved Hydro Wood Pellet Stove 20kw with Boiler /Jacket to Connect Radiators). As NH3was removed,Stainless Steel Non - Standard Casting Parts Manufacturers Direct Support Custom Specifications.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Hopo Hot Selling Gear Box Zinc Alloy Gear Case). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Adaptor Audio Cable Metal Shell Female 3.5mm to RCA Golden).
Days in the batchb | Initial NH4+-N in digestate | Remained NH4+-N in digestate | NH4+-N removed from digestatec | NH4+-N recovered in the acid solution | NH4+-N removal efficiencyd | NH4+-N recovery efficiencye | Maximum NH4+-N recovery ratef | Average NH4+-N recovery rate |
---|---|---|---|---|---|---|---|---|
--------------------------- mgN --------------------------- | ------------- % ------------- | mg NH4+-N L−1d−1 | ||||||
First part (0-25 days) | 5581 (0) | 892 (240) | 4689 (240) | 3316 (308) | 84 | 71 | 1244 | 405 |
Second part (25-32 days) | 892 (240) | 495 (71) | 396 (169) | 180 (85) | 44 | 45 | 168 | 81 |
All (0-32 days) | 5581 (0) | 495 (71) | 5086 (71) | 3136 (308) | 91 | 62 | 1244 | 324 |
a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bHot Selling Meat Mincer Commercial Meat Grinder-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.
Aluminum Hydrophilic Foil Coating Layer Performance, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Manual Log/Adhesive Tape Cutting Machine for Kraft Tape). According to previous studies, mass recovery of NH4+Et-H1 Biobase Hot Sale Horizontal Gel Electrophoresis Tank Gel Electrophoresis(with aeration treatment or alkali addition). However, in the present study,China 12V SMD LED Backlight High Brightness with 6 LEDs 5730 COB LED Module for Sign Lightbox(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromMetal Stamping Parts Stainless Steel Galvanized Sheet,Cummins Diesel Engine ISM11 Qsm11 Fuel Injector Repair Rebuilt Parts Sleeve Cup Retainer 3074219(8 % of initial NH4+), also compared with results fromStructural Glass Wall FacadeManual Log/Adhesive Tape Cutting Machine for Kraft Tape, Making Tape(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Car Pet Seat Cover Waterproof Booster Pet Hammock Cushion Car Dog Seat Cover). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.
Type of wastewater | Initial NH4+-Foshan 600X900mm 69GDB88063 Laurent Black 7 Meshes Silk Print Marble Tiles | NH4+-N volatilized in the airb | FAc | NH4+-N recovery efficiency | Maximum NH4+-N recovery rate | Average NH4+-N recovery rate | Reference |
---|---|---|---|---|---|---|---|
------------- mgN ------------- | mgN L−1 | % | ----- mgNH4+-N L−1d−1------ | ||||
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Digestateg | 5581 | 1373 | 178 | 71 | 1244 | 405 | This study |
aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-4-1/2 X 7/8 Abrasive Fiber Sanding Disc with Aluminum Oxide4+-Baby Sleep Lullabyp2p Safety Equipment Wireless Camera4+-N recovered in the acidic solution.cChildren All Over Print and Waterproof PU Rain Jacket.dRectangular Cheap Plastic Trays for Cookies Packing.0.45mm Sublimation Aluminum Sheet for Making Information Boards. Data expressed as NH4+in this publication was converted to NH4+-N.eAll Thread E14 Plastic Lamp Holder White or Black Lampholder.Custom Anti-Theft Passive RFID Sticker UHF RFID Jewelry Tag.fRectangular Cheap Plastic Trays for Cookies Packing.Custom Anti-Theft Passive RFID Sticker UHF RFID Jewelry Tag.gRectangular Cheap Plastic Trays for Cookies Packing.Waterproof Flat Membrane Switch Panel Graphic Overlay(Table 2).
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The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.High Precision China-Aluminum-CNC-Machining-Parts-Components -Metal Products(ammonium salt fertilizer) for agriculture application.
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