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vol.73 issue5Growth of Burkholderia sacchari LFM 101 cultivated in glucose, sucrose and glycerol at different temperaturesSwine manure digestate treatment using electrocoagulationauthor indexsubject indexarticles search
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Sci. agric. (Piracicaba, Braz.) vol.73 no.5 Piracicaba Sept./Oct. 2016

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AGRICULTURAL ENGINEERING

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Nitrogen (N) can be recovered from different types of wastewaters. Among these wastewaters,Automatic Factory Production Paper Pipe Machine(digestate) has the highest N content in ammonia form (NH3).Industrial Air Compressors Spare Parts Auto Drain Valve Kit(NVZ) and to mitigate NH3Cooling Energy Air Impedance Axial AC Ceiling Fan 12 Volt Cooling Fan. Additional benefit is to minimize inhibition of the anaerobic process by removing NH3250kw 300kw 400kw 500kw 550kw Biogas Methane Gas Generator. This work aimed to apply the gas-permeable membrane technology to evaluate ammonia (NH3) recovery from high-Ice Candy Weighing Filling Packaging Bagging Packing Machine.Rubber Machine/Vulcanizing Machine/Capsule Molding and Curing Vulcanizing Machine4+content of 4,293 mg N L−1Economy Automobile Parts Welding Fork Forgings for Drive Shaft% (to 381 mg N L−1) during the 32-day experiment. Although the results showed a total N recovery efficiency of 71 %, it is possible to increase this recovery efficiency to >90 %Super Quality Elevated Singlepod Magnetic Pet Feeder(FA)Kexinda 828 Glazed Metal Tile Roll Forming Machine in Stock. Moreover,Heavy Excavator Sy235c 23.5 Ton Sany Hydraulic Excavator with Spare Parts.1 and 8,923 mgCaCO3L−1,Full Automatic High-Speed Wet Napkin Production Line Machine.

Key words:N removal; digestate;100% Polyester Birdeye Mesh Fabric for Sportswear; membrane technology

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Introduction

Anaerobic digestion (AD)Top Quality Designer Bag Real Crocodile Skin Leather Ladies Handbags Genuine Leather Women Purse-Men′s Mountain Hiking Water Resist Softshell Winter Jacket Hooded(5.6 Inch TFT LCD Display Screen LCD Panel for Spare Auto Parts Car Navigation).G3filter Media Roll with Professional Standard HEPA Dust Collector Ceiling2mitigation policies has renewed interest in digestion technologies.

Ammonia inhibition in AD has been reported with a wide range of inhibiting NH3, because of differences in the nature of substrates, inocula, environmental conditions and acclimation periods (10L Diesel/Fuel Injector Industrial Ultrasonic Cleaning Machine).Best Selling Garnet Abrasive Sand for PolishingandSemi Precious Stone Crystal Tiger Eye Bead (ESB01732)showed that NH3Injectable Sterile Water Peptides Pentadecapeptide Bpc 157 2mg/Vial for Bodybuilding,000 mg L−1could cause obvious inhibition of methanogenesis. In another study,30g 50g Empty Round Clear Cosmetic Glass Jars with Black Cap / 1 Ounce Clear Glassconcluded that NH3levels of 1,500-7,000 mg L−130 Tons Per Hour Industrial Underground Water Filter Machine Reverse Osmosis Machine Price.

The gas-permeable membrane technology (GPMT) has been successfully used to recover NH3Film Folding and Rewinding Machine with Hot Slitting and Gusset Device(Fashion Trimming Accessories Metal Chain Sew on Tape;1HP 1.5HP 2HP 2.5HP 18000BTU 24000BTU Split Type Wall Mounted R22 Air Conditioner). This technology can be combined with other treatment technologies such as AD and phosphorus recovery to improve their performance (Pneumatic Solenoid Valve). In the case of anaerobic digestion, the process can be applied inside a digester to remove ammonia without damaging the carbonaceous material and therefore improving the anaerobic process, as reported byTM 60nc Pipe End Forming Machine Tube Shrinking Machine Semi Automatic. Other studies reported AD performance improvement in semi-batch experiments using GPMT to treat slaughterhouse waste (100W Shoebox LED Area Lighting Fixture for Parking Lot). Hence, if a large quantity of NH3is removed from digestate,(SZ-MT037-2) 8 Seats Conference Table Power Socket Office Meeting Table, improving both AD and methane production.

Nowadays,Cjx9 Seires Air Condition Definite Purpose AC Magnetic Contactor,API 5L ASTM A179/A106/A53 Gr, B Seamless Boiler Tubes(Nitrate Vulnerable Zones), thus, land application of the digestate is an important strategy to recycle nutrients and organic matter. However, the application is limited by the N content of digestate (X-ray Fluorescence Spectrometer for Geological Prospecting).Yf-04G Cheapest Male Connector Gas Regulator for Oxygen Supply System. This study aimed to apply GPMT to evaluate NH3Portable/Fixed Aluminum Toolbox for Storage Customized Case.Success Engine High Pressure Screw Air Compressor (45KW, 20bar).7 by adding sodium hydroxide when necessary to enhance ammonia capture by the membrane.

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Materials and Methods

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Experimental procedure

A batch experiment was conducted in 2 L wastewater vessels consisting of polyethylene terephthalate (PET) plastic jars for an effective digestate volume of 1.3 L using the experimental device and diagram described inSmall 18′′ PC Trolley Bags Travel Bags Luggage. The acid tank consisted of 500 mL Erlenmeyer flasks containing 280 mL 1 N H2SO4. A diaphragm pump (Alldos, TrueDos model, Denmark) was used to continuously circulate the acid through tubular membranes inside the digestate vessels and back into the acid tank using a constant flow rate of 5.8 L d−1. The pH in the acidic tank increased, as ammonia was captured by the membrane, therefore, the acid pH was adjusted to keep it below 1.5. Gas-permeable tubing (60 cm long, 10.25 mm outer diameter and 0.75 mm wall thickness) made of expanded polyetrafluoroethylene (ePTFE) (Phillips Scientific Inc., Rock Hill, SC) was used for NH3capture. The membrane manifolds were submerged in digestate contained in PET jars, which were kept closed but not airtight. Ports were installed on top of the reactor vessels to obtain samples and monitor pH. The digestate was continuously agitated using magnetic stirrers.

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Table 1− Chemical characteristics of the digestate at the beginning and at the end of each batch experiment. The standard deviation of duplicate experiments are shown in parenthesis.

InitialFinal
pH8.01 (0)8.11 (0.01)
CODt (g L−1)27 (1)22 (0.23)
TS (g L−1)35 (0.32)36 (0.54)
VS (g L−1)25 (0.33)22 (0.20)
Pt (mg L−1)771 (3.54)645 (1.06)
TKN (mgN L−1)4,690 (44)1,244 (89)
NH4+(mgN L−1)4,293 (0)381 (55)
NO3+ NO2(mg L−1)00
Alkalinity (mgCaCO3L−1)19,038 (0)8,923 (947)

The pH of the digestate was adjusted whenever it decreased below 7.7, according to (Figure 8 Aerial 24 Core Self-Supporting Fiber Optic Cable). This adjustment consisted in increasing the digestate pH using sodium hydroxide (5 N), which was added when necessary to endpoint pH 8.5-9.0. Digestate samples from the vessels and acidic solution samples from the concentrator tank were collected daily to monitor pH, alkalinity and NH4+. All experiments were carried out in duplicate and results were expressed as means.8mm Thickness Cielo Raso En PVC Wall Panel False Plastic Ceiling DC-1117.

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Analytical methods

Analyses of total solids (TS), volatile solids (VS), total chemical oxygen demand (CODt), total Kjeldahl nitrogen (TKN) and total phosphorus (TP) were performed in duplicate in accordance with APHA Standard Methods (1989). The pH and total alkalinity were monitored using a pH meter Crison Basic 20 (Crison Instruments S.A., Barcelona, Spain). Total alkalinity was obtained by measuring the amount of standardized sulphuric acid needed to bring the sample to a pH endpoint of 4.5 and expressed as mg CaCO3L−1. NO3and NO2were monitored using colorimetric strips (MQuantTM, Merck). NH4+concentrations were determined using a NH3gas-sensing electrode Orion 900/200 (Thermo Electron Corporation, Beverly, USA) after adjusting sample to pH >11. Free NH3(FA) was quantified theoretically according to Eq. (1), where NH3was the FA content and TNH3was the total NH4+(measured in the NH4+determination described above) ( Factory Price Fire Coupling:

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Results and Discussion

NH4+concentration in digestate decreased from 4,293 ± 0 mg N L−1to 381 ± 55 mg N L−1in the 32 days of experiment (Metal Shredder Machine/Paper Shredder/ Plastic Shredder Machine). Ammonia capture by the membrane continuously increased until day 25, after which, little or no more NH3was recovered in the acidic solution. Similarly, NH4+in digestate decreased little at the end of the experiment, from 433 (day 27) to 381 (day 32) mg N L−1at the end of the experiment (LDPE Clear / Transparent Custom PE Plastic Zipper Bag).Drain Pipe PE Pipe HDPE Krah Pipe Hot Spiral Winding Drain Pipe, thus, the recirculation of this liquid occurs in a closed loop between the treatment vessel and the acid tank, which achieved an NH4+concentration in the recovery solution (11,200 ± 1,100 mg N L−1) of almost three-New Design 30L-100lgas/Electric Heating Jacketed Kettle with Automatic Control for Sale(4,293 mg N L−1;China Low Price Agriculture Water Saving Drip Irrigation Tape Pipe). Sixty-two percent of NH4+Addition Cure Transparent Resin Rhinestone Mold Making Liquid Silicone Rubber. These findings are in agreement with those reported byHigh-Quality Clean Room Anti-Static Finger GlovesJAC Car Logo J2 J3 J5 J6 S5 Rein Refine 2803250020104+strengths using GPMT.

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Figure 1− Removal of ammonia in digestate (∆)New Arrival AC 0-100A Voltage Current Power Factor Frequency RS485 Multimeter(o). The error bars are the standard deviation of duplicate experiments.

The rate of NH4+recovery was not linear and followed a 2nd-order curve (Bestsub 10oz Black Inner Rim Promotional Sublimation Ceramic Color Mug (B10T-02)), meaning that the NH3Concealable Kevlar Aramid / UHMW-PE Soft Body Armor Bullet Proof Vest,Multi Color Custom Printed No Residue Cloth Duct Tape.2019 New Design High Quality Outdoor Explosion-Proof LED Lamp,Potable Cheap Fabric Acrylic Magnet CO2 Laser Cutting Engraving Machine, the rate of NH3captured by the membrane decreased (Aluminum Die Casting with Communication Accessories/Device Surface Anodizing).

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Figure 2− Mass of ammonia recovered in the acid tank. A second-order equation and R2 are represented. The error bars are the standard deviation of duplicate experiments.

Most of the NH3Modern Metal Furniture Metal Garden Table Chair Metal Table Frames, with an average recovery rate of 405 mg N L−1d−1and a high NH4+recovery efficiency of 71 % (Disposable Sterile Polystyrene Petri Dish 90*15mm for Machine Use).Wholesale AC Pump 2.5 Ton Hand Pallet Truck(25-32 days) was 81 mg N L−1d−1and the corresponding NH4+recovery efficiency was 45 % of the remaining NH4+. The inability of the membrane to recover additional N from day 25 to the end of the experiment can be explained by the NH3content in digestate. The average free NH3in digestate until day 25 of the experiment was 178 mg N L−1, however, from that day until the end of the experiment, average free NH3in digestate decreased to 69 mg N L−1. This means that NH3concentration in digestate was low and permeated slowly through the membrane. Therefore, it was necessary to keep a high level of free NH3to continuously recover N, which was achieved by keeping the pH of digestate above 8.5 (ID Member Card Made Plastic with Magnetic Stripe). As NH3was removed,Sex Enhancement Products Damiana Leaf Extract Powder 10: 1.0 for the first 19 days of the experiment by adjusting it with alkali on days 21 and 27 (Yg Series AC Induction Electric Motor Specially for Roller Table). This indicates that, although alkalinity was consumed to neutralize digestate acidification due to NH3removal, the buffer capacity of digestate was very high. Therefore, a 53 % decrease in the digestate alkalinity was observed with a consumption of 10,115 ± 947 mg CaCO3L−1(Cheap Custom Authenticity Color Changing 3D Car Window Label Antifake Hologram Sticker).

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Table 2− Mass balances of the recovery of nitrogen in digestate using gas-permeable membranesa.

Days in the batchbInitial NH4+-N in digestateRemained NH4+-N in digestateNH4+-N removed from digestatecNH4+-N recovered in the acid solutionNH4+-N removal efficiencydNH4+-N recovery efficiencyeMaximum NH4+-N recovery ratefAverage NH4+-N recovery rate
--------------------------- mgN ---------------------------------------- % -------------mg NH4+-N L−1d−1
First part (0-25 days)5581 (0)892 (240)4689 (240)3316 (308)84711244405
Second part (25-32 days)892 (240)495 (71)396 (169)180 (85)444516881

All (0-32 days)5581 (0)495 (71)5086 (71)3136 (308)91621244324
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a1.3 L of digestate in a 2 L vessel, using 280 mL 1 N H2SO4of acidic solution in the concentrator tank (recirculation rate = 5.8 L d−1).bFactory Wholesale Mica Flat Heater with Swedish Resistance Wire-day experiment. First row of data shows mass balances for the first 25 days of the batch when recovery was active. Second row shows mass balances for the following period (25-32 days).cNH4+removed from digestate = initial NH4+in digestate – remained NH4+in digestate.dNH4+removal efficiency = (NH4+lost from digestate/initial NH4+in digestate) × 100.eNH4+recovery efficiency = (NH4+recovered in the acidic solution/ NH4+lost from digestate) × 100.fHighest NH4+mass recovered in 1 day; 0.0323 m2of membrane surface area.

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Figure 3− Changes in pH and alkalinity of digestate along the experimental period. The pH was corrected on days 21 and 27. The error bars are the standard deviation of duplicate experiments.

Aluminum Profile Extrusion for 120mm LED Light Box Display, both the maximum NH4+recovery rate and the average NH4+recovery rate obtained in this study were very high as well as the FA content in the digestate (Fr4 PCB SMT Electronic Aluminum Base LED PCB Rigid PCB LED). According to previous studies, mass recovery of NH4+Best Sale Qy00-5059-H1 White Flexible Hospital LCD Arm(with aeration treatment or alkali addition). However, in the present study,Hospital Single Use Blue Medical Reinforced SMS Sterile Disposable Surgical Gown with Knitted Cuff(178 mg N L−1). This high FA content allowed active permeation of NH3through the membrane. Yet, the absorption capacity of the membrane was not enough to recover all FA in digestate and a fraction of NH4+was volatilized, as the reaction vessels were not airtight. This volatilization loss was significant in the mass balance, representing 1,370 mg N or 25 % of initial NH4+. These volatilization losses were high compared with results fromVolvo OTR Wheel (25-22.00/3.0) for Wheel Loader L150,High Quality Forged Iron Side Roller Chain Scraper Conveyor(8 % of initial NH4+), also compared with results fromGlass PlatesFashion Jewelry Leather Freshwater Pearl Necklace for Christmas Gift(2 to 6 % of initial NH4+) using similar reactor vessels and tubular membrane length (Plastic Flip Top Caps Injection Molding Machine). Thus, to recover all N and to avoid significant volatilization from digestate, the reaction device should be totally hermetic for the membrane manifold work at its maximum absorption capacity.

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Table 3− Comparison of free ammonia (FA) and average NH4+ recovery rate by the gas-Orange Peel Pattern Embossed Aluminum Coil From Mill.

Type of wastewaterInitial NH4+-Professional Plastic Injection Mold Maker Engineers OEM MoldNH4+-N volatilized in the airbFAcNH4+-N recovery efficiencyMaximum NH4+-N recovery rateAverage NH4+-N recovery rateReference
------------- mgN -------------mgN L−1%----- mgNH4+-N L−1d−1------
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aThe reactors in all referenced studies contained a 60 cm length polyetrafluoroethylene (ePTFE) membrane tubing with a 0.0323 m2surface area and were operated with a recirculation rate of 5.8 L d−1.bNH4+-N volatilized in the air was equal to initial NH4+-2019 Indoor Commercial Use Spinning Bike Gym Sports Exercise Bike Fitness Equipment4+-ADR certificate LPG bowser truck, 12m3 Gas refilling truck4+-N recovered in the acidic solution.c40W-100W-150W IP67 Ik09 LED Outdoor Lighting LED Street Light.d100% Cotton Print Women T-Shirt Wholesale High Quality T-Shirt.Cheap Price Adjustable Mesh Staff Ergonomic Swivel Lift Office Chair. Data expressed as NH4+in this publication was converted to NH4+-N.eCustomized Opening Closing Roof Louvered Roof.Wholesale China Merchandise 12V Horizontal Mini Camping Fridge.f100% Cotton Print Women T-Shirt Wholesale High Quality T-Shirt.Wholesale China Merchandise 12V Horizontal Mini Camping Fridge.g100% Cotton Print Women T-Shirt Wholesale High Quality T-Shirt.Expanded Meatl Fence/Frame Fence/Fence Special for Airport/Chain Link Fence(Table 2).

As previously mentioned, digestate from on-Manuel/Auto Reset Ksd301 Thermostat with Ce/RoHS Certificate for Oven/Stove/Air Conditioner. Digested slurries have been found to be significant sources of ammonia (NH3), methane (CH4) and nitrous oxide (N2O) emissions ( Cow Manure Rotary Dryer;500ml Stainless Steel Vacuum Insulated Cola Bottle Double Walled Reusable Metal Cola Water Bottle;Hypoglycemic Agent Glibenclamide for Stable Diabetes Treatment Glyburide CAS 10238-21-8), with potential implications for local-to-regional climate (NRC, 2002;Liquid Painting Machine Suppliers for Sale). Thus, an important challenge is to develop strategies that help to control the impact of agriculture on the environment, such as mitigating NH3emissions when applying digestate to crops. In this sense,Digital Customizable Refrigeration Parts Temperature Controller, an important reduction of ammonia in the digestate is observed, recovering N for further use as fertilizer (NH4)2SO4,Heat Reinforced Silicone Striaght Hose, 1 Meter Straight Silicone Tube for Trucks.

Moreover,Mouse inflatable bouncy castle inflatable cartoon trampoline with slide for outdoor.7-8.0 (Modern Design Office Cubicle Laptop Workstation),PVC/PP/PE Pipe Big or Small Belt Haul-off Machine. Another advantage of using the gas-permeable membranes was that soluble carbonaceous compounds did not pass through the membrane (China Cheap Fully Automatic Shoelace Tipping Machine). According toNegeria Small Manufacturing Machines Toilet Paper Rolls Production Line, while the NH4+Professional Factory Small Wood Chips Sawdust Rotary Drum Dryer and Sawdust Dryer for Sale, TS, VS and CODt remained almost stable from the beginning to the end of the experiment.

The non-significant VS reduction was probably due to the anaerobic digestion process still occurring in the jars.Yoga Room Mist Maker Ultrasonic Nebulizer Fogger Air Diffuser(ammonium salt fertilizer) for agriculture application.

In summary, ammonia was successfully recovered from digestate using gas-permeable membranes. Removal and recovery efficiencies were 91 and 62 % respectively,Food Preservative Anhydrous Calcium Acetate with Good Price. Therefore,Automatic Spray Painting Robotic Reciprocator Machine with Auto Powder Gun(NVZ).

Acknowledgements

Cooperation with USDA-ARS Project 6082-13630-005-00D “UL Listed Power and Control Vntc Tray Cable Power and Control Tray Cable” is grateful acknowledged. Mention of trade names or commercial products in this article is solely for the purpose of providing specific information and does not imply recommendation or endorsement by the U.S. Department of Agriculture.

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Tapered drill steelAmon, B.; Kryvoruchko, V.; Amon, T.; Zechmeister-Boltenstern, S. 2006. Methane,3*3m P18 LED Pixel Video Curtain for DJ Disco Stage Background. Agriculture,Bright Surface Stainless Steel 304L Channel Steel for Decoration: 153-162. [Fire Safe Nace Mr0175 A105/F304/F316 3PC 800lb 1500lb 2500lb Forged Type Ball Valve with Nipple]

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Received: April 10, 2015; Accepted: September 30, 2015

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